Liquid atomization is a largely widespread unit operation. The disintegration of a liquid into droplets depends on the nature of the nozzle, on the process parameters as well as physicochemical characteristics of the fluid. The aim of this work is to study the contribution of the process (liquid outlet speed and air pressure) and physicochemical (viscosity and surface tension) factors on the size distribution of droplets generated by single- and two-fluid flat spray nozzles. The obtained droplet median diameters which range between 77 and 594 mu m for the single-fluid nozzle and between 11 and 599 mu m for the two-fluid nozzle, are discussed in relation with operating conditions of atomization process. Dimensional analysis was performed as a modeling approach. Despite energy input for the droplet formation is known to be influenced by different origins according to single and two-fluid nozzles, it is shown that a unique correlation, with specific values of parameters for each nozzle type, gathers all the parameters affecting droplet size. In the range of process and formulation parameters tested, this correlation is validated and gives satisfactory agreement for the single- and two-fluid nozzles
Aroma compounds are known to be efficient active agents for a broad range of applications (antimicrobial, anti-oxidant, insect repellent…) that are highly sought when aiming at extending shelf life of food or biological products. However, they are intrinsically odorant and volatile at ambient temperature, which restricts the processing routes used to introduce them in a polymeric matrix and can affect their mode of action and limit efficiency. Indeed, due to their high sensitivity toward temperature they can be lost or transformed during processing. Acting after being released in the headspace, their concentration has to be controlled to avoid any odorant contamination of the targeted products. Hence, the ability for an aroma compound to be retained in a polymeric matrix, and then released when submitted to a triggering effect, are the two main requirements that should be satisfied. The volatile nature of the aroma compound offer the possibility when introduce in the packaging to act by direct or indirect contact with the product and thus to be used in different ways; as a coating layer directly applied on the product surface, as a self-supported film or as coated paper when associated with a paper sheet, as well as an object that could be inserted in the package. As biopolymers such as proteins and polysaccharides are able to retain aroma compounds but also to favor their release by modification of their structure when the relative humidity (RH) and temperature change, they are relevant carriers of these specific aroma compounds. Examples of how active packaging systems with limonene, eugenol and carvacrol as active agents were designed and elaborated. These examples will be presented with a special focus on the processing conditions and the way to improve their aroma compound retention and the release control (biopolymer nature, cyclodextrin clay addition…). Avrami's equation has been used to model the transfer of aroma compound and to advantageously compare it taking into account the mechanism in relation to the biopolymer structural changes.
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