Thomas R. Wagler scite author profile

An optically active cyclam ligand bearing a functionalized side chain appended to a ring carbon and its nickel(i1) complex are readily prepared from a diamino acid precursor.Among the wealth of macrocyclic polyamine ligands the cyclamt family has enjoyed particular favour for its ability to impart kinetic and thermodynamic stability to various oxidation states of ligated transition metals.l.2 Recently, cyclam derivatives bearing functionalized side chains have been investigated wherein the pendant group may provide either an additional ligating site or a point of further synthetic elabora-? Cyclam = 1,4,8,11-tetra-azacyclotetradecane.

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Thomas R. Wagler

High turnover rates in pH-dependent alkene epoxidation using NaOCl and square-planar nickel(II) catalysts

Alkene Epoxidation Using Ni(II) Complexes of Chiral Cyclams

Optically active difunctionalized dioxocyclam macrocycles: ligands for nickel-catalyzed oxidation of alkenes

Synthesis of an optically active C-funtiopnalized cyclam: (S)-5-(hydroxymethyl)-1,4,8,11-tetra-azacyclotetradecane and itws nickel(II) complex

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