Geopolymer synthesis has two main requirements to fulfil which are the source material that is rich in Silicon (Si) and Aluminum (Al) and alkali activator such as sodium/potassium hydroxide. Sodium hydroxide (NaOH) is widely used for the synthesis of geopolymer compared to potassium hydroxide (KOH) with addition of silicate solution for the purpose of increasing dissolution process. However, the comparison of using different activator in the absence of silicate solution for geopolymer synthesis is not well established. This paper presents an evaluation on compressive strength of fly ash–based geopolymer by using different activator (KOH and NaOH) with respect to different curing conditions (time and temperature) in the absence of sodium silicate. The samples were mixed using mortar mixer and prepared in 50mm x 50mm x 50mm mould for determination of compressive strength. It can be observed that the highest compressive strength up 65.28 MPa was obtained using NaOH. Meanwhile, synthesis using KOH only recorded 28.73 MPa. The compressive strength was better when cured at elevated temperature (60°C) than room temperature (25°C). Further analysis on the microstructure of the highest compressive strength geopolymer samples for both activators was carried out using Field Emission Scanning Microscopy (FESEM) and Raman spectroscopy.
Geopolymer is produced from the alkali activation of materials rich in Si and Al such as fly ash. Based on the experimental and characterization result, solid to liquid ratio influenced the setting time and compressive strength of geopolymer in order to have good mechanical property. The optimum setting time and compressive strength were obtained at 3 : 1 solid to liquid ratio. Optimum curing time reach at 14 days.
Geopolymer is produced from the alkali activation of materials rich in Si and Al such as fly ash. Sodium hydroxide (NaOH) with high concentration is normally used in geopolymerization. Limited research has been done with low concentration of alkali activator. This study confirms that KOH with low concentration affect the setting time and compressive strength of geopolymer in order to have good mechanical properties. Optimum result was observed at 4.5 M KOH. This result can be further developed to produce geopolymer with low alkaline activator for coating applications.
Geopolymer is produced from the alkali activation of materials rich in Si and Al with addition of silicate solution in order to improve the mechanical property. Limited research has been done with the absence of silicate solution in the geopolymerization process by varying solid/liquid ratio and on how it works for that condition on mechanical and physical properties. This paper presents an investigation on the mechanical and physical properties of fly ash based geopolymer by varying solid to liquid ratio using sodium hydroxide as the only activator. In addition, the strength development also been investigated. The samples were prepared using 50mm x 50mm x 50mm mould and cured at an elevated temperature (60oC). It can be observed that the optimum compressive strength and density were obtained at solid/ liquid ratio of 4. In addition, the compressive strength of fly ash based geopolymer for all the solid to liquid ratio increased until 14 days and started to decrease later.
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