How to develop efficient red-emitting organometallics of earth-abundant copper­(I) is a formidable challenge in the field of organic light-emitting diodes (OLEDs) because Cu­(I) complexes have weak spin-orbit coupling and a serious excited-state reorganization effect. Here, a red Cu­(I) complex, MAC*-Cu-DPAC, was developed using a rigid 9,9-diphenyl-9,10-dihydroacridine donor ligand in a carbene-metal-amide motif. The Cu­(I) complex achieved satisfactory red emission, a high photoluminescence quantum yield of up to 70%, and a sub-microsecond lifetime. Thanks to a linear geometry and the acceptor and donor ligands in a coplanar conformation, the complex exhibited a high horizontal dipole ratio of 77% in the host matrix, first demonstrated for coinage metal­(I) complexes. The resulting OLEDs delivered high external quantum efficiencies of 21.1% at a maximum and 20.1% at 1000 nits, together with a red emission peak at ∼630 nm. These values represent the state-of-the-art performance for red-emitting OLEDs based on coinage metal complexes.

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ObjectiveThe objective of this research was to study the electrical properties and quality of frozen-thawed chicken breast meat and to investigate the relationship between these parameters at different times of frozen storage.MethodsThawed samples of chicken breast muscles were evaluated after being kept in frozen storage at −18°C for different periods of time (1, 2, 3, 4, 5, 6, 7, and 8 months).ResultsThe results showed that water-holding capacity (WHC) and protein solubility decreased while thiobarbituric acid-reactive substances content increased with increasing storage time. The impedance module of samples decreased during 8-month frozen storage. Pearson correlation coefficients showed that the impedance change ratio (Q value) was significantly (p<0.05) related to pH, color, WHC, lipid oxidation and protein solubility, indicating a good relationship between the electrical properties and qualities of frozen-thawed chicken breast meat.ConclusionImpedance measurement has a potential to assess the quality of frozen chicken meat combining with quality indices.

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Hierarchical linear control scheme is widely used in ac microgrids. However, its transient response is slow and parameter tuning is time-consuming. Finite Control Set-Model Predictive Control (FCS-MPC) strategy has desired dynamic performance. Nevertheless, it requires an additional sensor to measure the inductor current. This article aims to mitigate these problems by introducing an improved FCS-MPC strategy for paralleled Voltage Source Inverters (VSIs). A capacitor current estimator is employed to reduce the extra current sensor in each VSI. The proposed control scheme consists of two loops: voltage reference generation loop and voltage tracking loop. The voltage reference generation loop achieves accurate load power sharing using virtual impedance-based droop control. Thus, communication is unnecessary among parallel VSIs. The voltage tracking loop utilizes a modified FCS-MPC block with capacitor current estimator to regulate the VSI output voltage. In order to verify the concept of the proposed control strategy, an ac microgrid consisting of two paralleled VSIs is implemented in dSPACE DS1202 hardware-in-theloop platform. Then a single VSI hardware prototype is implemented and tested experimentally. The proposed method has the merits of good extensibility, low system cost and compact structure. Its steadystate performance is competitive with hierarchical linear control, while the transient response is significantly improved.