Abstract. The Zugspitze Geodynamic Observatory Germany has been set up with a worldwide unique installation of a superconducting gravimeter at the summit of Mount Zugspitze. With regard to hydrology, this karstic high-alpine site is largely dominated by high precipitation amounts and a long seasonal snow cover period with significant importance for water supply to its forelands, while it shows a high sensitivity to climate change. However, regarding the majority of alpine regions worldwide there is only weak knowledge on temporal water storage variations due to only sparsely distributed hydrological and meteorological point sensors and the large variability and complexity of alpine signals. This underlines the importance of well-equipped areas such as Mount Zugspitze serving as natural test laboratories for an improved monitoring, understanding and prediction of alpine hydrological processes. The observatory superconducting gravimeter OSG 052 supplements the existing sensor network as a novel hydrological sensor system for the direct observation of the integral gravity effect of total water storage variations in the alpine research catchment Zugspitze. Besides the experimental setup and the available datasets, the required gravimetric prerequisites are presented such as calibration, tidal analysis and signal separation of the superconducting gravimeter observations from the first 2 years. The snowpack is identified as primary contributor to seasonal water storage variations and thus to the gravity residuals with a signal range of up to 750 nm/s2 corresponding to 1957 mm snow water equivalent measured at a representative station at the end of May 2019. First hydro-gravimetric sensitivity analysis are based on simplified assumptions of the snowpack distribution within the area around Mount Zugspitze. These reveal a snow-gravimetric footprint of up to 4 km distance around the gravimeter with a dominant gravity contribution from the snowpack in the Partnach spring catchment. This study already shows that the hydro-gravimetric approach can deliver important and representative integral insights into this high-alpine site. This work is regarded as a concept study showing preliminary gravimetric results and sensitivity analysis for upcoming long-term hydro-gravimetric research projects.

addition (that is regeneration by oxygen) is assured. A very important means for adjusting the metal-oxygen bond energy of an oxide is by reacting it with another material to produce a new structure with modified bond energies and surface geometry (such as a series of vanadate compounds starting with the alkali vanadates and perhaps ending with heteropoly vanadic acids).The experimental results described here are consistent with the proposed hypothesis, but there are obvious complicating factors. For example oxygen diffusion from bulk to surface and the reverse process tend to distort somewhat the site distributions of the surfaces from those described in the models. Also phase boundaries, dislocations, and other forms of surface disorder add further complications to the case of real surfaces. However in spite of these complications there is a clearly distinguishable correlation between the approximate surface configuration as described by the model and the selectivity factor in the oxidation of propylene to acrolein. Rates of carbon dioxide absorption by 0.01, 0.05, and 0.1 molar sodium hydroxide solutions were measured a t 25OC. for exposure times from 1.4 to 21.6 milliseconds with a laminar-jet technique. Absorption rates were calculated with a model based on one-dimensional diffusion occurring simultaneously with two consecutive irreversible chemical reactions. The resulting partial differential equations were solved with an IBM-709 computer. The calculated absorption rates agreed within 5 % of the experimental values.This work is part of an extensive study of the equilibrium, kinetics, and mass transfer characteristics of the system defined by the overall reaction marily with the unsteady state absorption of carbon dioxide by alkaline solutions. The following reactions were considered:NaHS + C02 + H2O e H2S + NaHC03 (1) The vapor-liquid equilibrium properties of this system have been reported previously (18) as have the reaction kinetics of the individual reactions which together give reaction (1) (14, 15).

Abstract. GFZ (German Research Centre for Geosciences) set up the Zugspitze Geodynamic Observatory Germany with a worldwide unique installation of a superconducting gravimeter at the summit of Mount Zugspitze on top of the Partnach spring catchment. This high alpine catchment is well instrumented, acts as natural lysimeter and has significant importance for water supply to its forelands, with a large mean annual precipitation of 2080 mm and a long seasonal snow cover period of 9 months, while showing a high sensitivity to climate change. However, regarding the majority of alpine regions worldwide, there is only limited knowledge on temporal water storage variations due to sparsely distributed hydrological and meteorological sensors and the large variability and complexity of signals in alpine terrain. This underlines the importance of well-equipped areas such as Mount Zugspitze serving as natural test laboratories for improved monitoring, understanding and prediction of alpine hydrological processes. The observatory superconducting gravimeter, OSG 052, supplements the existing sensor network as a novel hydrological sensor system for the direct observation of the integral gravity effect of total water storage variations in the alpine research catchment at Zugspitze. Besides the experimental set-up and the available data sets, the gravimetric methods and gravity residuals are presented based on the first 27 months of observations from 29 December 2018 to 31 March 2021. The snowpack is identified as being a primary contributor to seasonal water storage variations and, thus, to the gravity residuals with a signal range of up to 750 nm s−2 corresponding to 1957 mm snow water equivalent measured with a snow scale at an altitude of 2420 m at the end of May 2019. Hydro-gravimetric sensitivity analysis reveal a snow–gravimetric footprint of up to 4 km distance around the gravimeter, with a dominant gravity contribution from the snowpack in the Partnach spring catchment. This shows that the hydro-gravimetric approach delivers representative integral insights into the water balance of this high alpine site.

Abstract. To assist atmospheric monitoring at high-alpine sites, a statistical approach for distinguishing between the dominant air masses was developed. This approach was based on a principal component analysis using five gas-phase and two meteorological variables. The analysis focused on the Schneefernerhaus site at Zugspitze Mountain, Germany. The investigated year was divided into 2-month periods, for which the analysis was repeated. Using the 33.3 % and 66.6 % percentiles of the first two principal components, nine air mass regimes were defined. These regimes were interpreted with respect to vertical transport and assigned to the BL (recent contact with the boundary layer), UFT/SIN (undisturbed free troposphere or stratospheric intrusion), and HYBRID (influences of both the boundary layer and the free troposphere or ambiguous) air mass classes. The input data were available for 78 % of the investigated year. BL accounted for 31 % of the cases with similar frequencies in all seasons. UFT/SIN comprised 14 % of the cases but was not found from April to July. HYBRID (55 %) mostly exhibited intermediate characteristics, whereby 17 % of the HYBRID class suggested an influence from the marine boundary layer or the lower free troposphere. The statistical approach was compared to a mechanistic approach using the ceilometer-based mixing layer height from a nearby valley site and a detection scheme for thermally induced mountain winds. Due to data gaps, only 25 % of the cases could be classified using the mechanistic approach. Both approaches agreed well, except in the rare cases of thermally induced uplift. The statistical approach is a promising step towards a real-time classification of air masses. Future work is necessary to assess the uncertainty arising from the standardization of real-time data.

<p>The warming of alpine bedrock permafrost in the last three decades and consequent reduction of frozen areas has been well documented. Its consequences like slope stability reduction put humans and infrastructures at high risk. 2020 in particular was the warmest year on record at 3000m a.s.l. embedded in the warmest decade.</p><p>Recently, the development of electrical resistivity tomography (ERT) as standard technique for quantitative permafrost investigation allows extended monitoring of this hazard even allowing including quantitative 4D monitoring strategies (Scandroglio et al., in review). Nevertheless thermo-hydro-mechanical dynamics of steep bedrock slopes cannot be totally explained by a single measurement technique and therefore multi-approach setups are necessary in the field to record external forcing and improve the deciphering of internal responses.</p><p>The Zugspitze Kammstollen is a 850m long tunnel located between 2660 and 2780m a.s.l., a few decameters under the mountain ridge. First ERT monitoring was conducted in 2007 (Krautblatter et al., 2010) and has been followed by more than one decade of intensive field work. This has led to the collection of a unique multi-approach data set of still unpublished data. Continuous logging of environmental parameters such as rock/air temperatures and water infiltration through joints as well as a dedicated thermal model (Schröder and Krautblatter, in review) provide important additional knowledge on bedrock internal dynamics. Summer ERT and seismic refraction tomography surveys with manual and automated joints’ displacement measurements on the ridge offer information on external controls, complemented by three weather stations and a 44m long borehole within 1km from the tunnel.</p><p>Year-round access to the area enables uninterrupted monitoring and maintenance of instruments for reliable data collection. “Precisely controlled natural conditions”, restricted access for researchers only and logistical support by Environmental Research Station Schneefernerhaus, make this tunnel particularly attractive for developing benchmark experiments. Some examples are the design of induced polarization monitoring, the analysis of tunnel spring water for isotopes investigation, and the multi-annual mass monitoring by means of relative gravimetry.</p><p>Here, we present the recently modernized layout of the outdoor laboratory with the latest monitoring results, opening a discussion on further possible approaches of this extensive multi-approach data set, aiming at understanding not only permafrost thermal evolution but also the connected thermo-hydro-mechanical processes.</p><p> </p><p> </p><p>Krautblatter, M. et al. (2010) ‘Temperature-calibrated imaging of seasonal changes in permafrost rock walls by quantitative electrical resistivity tomography (Zugspitze, German/Austrian Alps)’, Journal of Geophysical Research: Earth Surface, 115(2), pp. 1–15. doi: 10.1029/2008JF001209.</p><p>Scandroglio, R. et al. (in review) ‘4D-Quantification of alpine permafrost degradation in steep rock walls using a laboratory-calibrated ERT approach (in review)’, Near Surface Geophysics.</p><p>Schröder, T. and Krautblatter, M. (in review) ‘A high-resolution multi-phase thermo-geophysical model to verify long-term electrical resistivity tomography monitoring in alpine permafrost rock walls (Zugspitze, German/Austrian Alps) (submitted)’, Earth Surface Processes and Landforms.</p>