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For the first time the macrokinetics of polymeranalogous reaction in a homopolymer globule is considered theoretically. Using mathematical apparatus of the theory of markovian stochastic processes we examined the statistical characteristics of the chemical structure of the emerging copolymers. It is shown that when the reaction is kinetically-controlled the sequence distribution of monomeric units in copolymer chains follows Bernoullian statistics. In the opposite regime, when the reaction is diffusion-controlled it is proved that the resulting primary structure is described by the Levy flight distribution. Such copolymers with nonmarkovian character of the alteration of units in macromolecules can not be synthesized in the bulk or in concentrated solutions by means of standard synthetic polymerization procedures.

The computation of the spectrum of a waveguide with arbitrary anisotropy with spatial dependence is a challenging task due to the coupling between axial and azimuthal harmonics. This problem is tackled in cylindrical coordinates by extending a spectral method for the general case. By considering the matrix representation of the operator on the right-hand side of the governing equations, the latter are exactly reformulated as an infinite set of integro-differential equations. Essential part of this study is taking into account the coupling of different harmonics, which becomes evident from the kernels of these equations. Provided a waveguide is translationally invariant in the axial direction, the coupling of axial harmonics vanishes. A practical approximation and truncation procedure yields a generalized eigenvalue problem, which can be solved numerically to obtain the entire spectrum of the operator and to construct the dispersion curves for the eigenmodes. The spectral method is tested against the results from the measurements of dispersion curves for the monopole, dipole, and quadrupole normal modes of scaled boreholes in tilted transverse isotropy anisotropic rock sample. Besides, the comparison of dispersion curves calculated by the spectral method and those computed from the synthetic data is discussed.

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