For local non-archimedean fields of characteristic 0 or sufficiently large, with odd residual characteristic, we explicitly parametrize and count the rational nilpotent adjoint orbits in each algebraic orbit of orthogonal and special orthogonal groups, and then separately give an algorithmic construction for representatives of each orbit. We then, in the general setting of groups GL n (D), SL n (D) or classical groups, give a new characterisation of the "building set" (defined by DeBacker) related to an sl 2 (k)-triple in terms of the building of its centralizer. Using this, we prove our construction realizes DeBacker's parametrization of rational nilpotent orbits via elements of the Bruhat-Tits building.
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