The physics base for the ITER Physics Design Guidelines is reviewed in view of application to DEMO and areas are pointed out in which improvement is needed to arrive at a consistent set of DEMO Physics Design Guidelines. Amongst the proposed improvements, the area of power exhaust plays a crucial role since predictive capability of present-day models is low and this area is expected to play a major role in limiting DEMO designs due to the much larger value of Ptot/R in DEMO than in present-day devices and even ITER.

Dendronization of a hyperbranched polyester with different generation dendrons leads to pseudo-dendritic structures. The hyperbranched core is modified by the divergent coupling of protected monomer units to the functional groups. Compared to dendrimers, the synthetic effort is significantly less, but the properties are very close to those of high-generation dendrimers. The number of functional groups, molar mass, and rheology behavior even in the early generation (G1-G4) pseudo-dendrimers strongly resembles the behavior of dendrimers in higher generations (G5-G8). Comparison of the segmental and internal structure with perfect dendrimers is performed using SANS, dynamic light scattering and viscosity analysis, microscopy and molecular dynamics simulation. The interpretation of the results reveals unique structural characteristics arising from lower segmental density of the core, which turns into a soft nano-sphere with a smooth surface even in the first generation.

A pseudo-dendritic structure clear of linear units is obtained from a hyperbranched aliphatic-aromatic polyester core modified by a B-protected AB(2) monomer. The chosen sequence of reaction and deprotection steps yields four generations of pseudo-dendrimers with either silyl- or OH-terminal units. (1)H and (13)C NMR confirm the extent of modification and the degree of branching in the different generations. The influence of generation number, end group type, and degree of branching on the specific solution behavior of the pseudo-dendrimers is investigated by size-exclusion chromatography coupled to static light scattering and by intrinsic viscosity characterization. Apparent density and scaling parameters indicate increased compactness of the pseudo-dendrimers with increasing generation number.

As a convenient alternative to the classical melt polycondensation the one‐pot solution polycondensation of suitable AB2 monomers under mild conditions has been successfully adapted to hyperbranched all‐aromatic polyester with phenol terminal groups. The polymerization was performed in solution at room temperature directly using commercially available 3,5‐dihydroxybenzoic acid as monomer and 4‐(dimethylamino) pyridinium 4‐tosylate as catalyst to suppress the formation of N‐acylurea. Different carbodiimides as coupling agents were investigated to find the optimal esterification conditions. The polymers have been characterized extensively and were compared with their well‐known analogs synthesized in melt. The characterization was carried out by NMR spectroscopy, size exclusion chromatography, and asymmetric flow‐field flow fractionation as an alternative separation technique for multifunctional polymers. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5158–5168, 2009