Air moisture of oceanic origin can be subject to long-range transport and could contribute to precipitation at distant places. With ongoing climate change the relationship between water vapour sources and sinks is under constant evolution and plays an important role for water budget assessments. This study analysed monthly integrated and event-based precipitation samples from two field sites in the Western Pamir Mountains (Tajikistan) for stable isotope compositions of oxygen (d 18 O) and hydrogen (d 2 H) of water. The aim was to investigate water vapour sources and, in particular, to evaluate contributions of water vapour from the Mediterranean region. The latter has been often postulated as a potential moisture source region for Central Asia. Deuterium excess values (d), that serve as a fingerprint of moisture origin, were below 13& in monthly integrated samples, for most of the year. This indicates a smaller contribution of high Mediterranean moisture ($20&) to the Western Pamir Mountains than originally expected. A maximum d value of 19& was observed in March, which is not in agreement with the common observation of increased Mediterranean contribution during winter (DJF). A Lagrangian backward trajectory model (HYSPLIT) was applied to infer the general air mass origin for sampled precipitation events. A maximum contribution of 'western' moisture of 40% was also detected in March, while 40%-60% of moisture that contributed to precipitation events in winter was transported by trajectories that originated from the Northern Indian Ocean.

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<p><strong>Abstract.</strong> Climate models are in need of improved constraints for water vapor transport in the atmosphere and tritium can serve as a powerful tracer in the hydrological cycle. Although general principles of tritium distribution and transfer processes within and between the various hydrological compartments are known, variation on short timescales and aspects of altitude dependence are still under debate. To address questions for tritium sources, sinks and transfer processes, sampling of individual precipitation events in Corte on the island of Corsica in the Mediterranean Sea was performed between April 2017 and April 2018. Tritium concentrations of 46 event samples were compared to their moisture origin and corresponding air mass history. Air mass back-trajectories were generated from the novel high-resolution ERA 5 data set of the ECMWF (European Centre for Medium-Range Weather Forecasts). Geographical source regions of similar tritium concentrations were predefined using generally known tritium distribution patterns, such as a <q>continental effect</q>, and from data records derived at long-term measurement stations of tritium in precipitation across the working area. Our model-derived source region tritium concentrations agreed well with annual mean station values. Moisture that originated from continental Europe and the Atlantic Ocean was most distinct regarding tritium concentrations with values up to 8.8 TU and near 0 TU, respectively. Seasonality of tritium values ranged from 1.6 TU in January to 10.1 TU in May and exhibited well-known elevated concentrations in spring and early summer due to increased stratosphere-troposphere exchange. However, this pattern was interrupted by extreme events. The average altitude of trajectories correlated with tritium concentrations in precipitation, especially in spring and early summer and if outlier values of extreme tritium concentrations were excluded. However, in combination with the trajectory information, these outlier values proved to be valuable for the understanding of tritium movement in the atmosphere. Our work shows how event-based tritium research can advance the understanding of its distribution in the atmosphere.</p>

Abstract. Climate models are in need of improved constraints for water vapor transport in the atmosphere, and tritium can serve as a powerful tracer in the hydrological cycle. Although the general principles of tritium distribution and transfer processes within and between the various hydrological compartments are known, variation on short timescales and aspects of altitude dependence are still under debate. To address questions regarding tritium sources, sinks, and transfer processes, the sampling of individual precipitation events in Corte on the island of Corsica in the Mediterranean Sea was performed between April 2017 and April 2018. Tritium concentrations of 46 event samples were compared to their moisture origin and corresponding air mass history. Air mass back-trajectories were generated from the novel high-resolution ERA5 dataset from the ECMWF (European Centre for Medium-Range Weather Forecasts). Geographical source regions with similar tritium concentrations were predefined using generally known tritium distribution patterns, such as the “continental effect”, and from data records derived at long-term measurement stations of tritium in precipitation across the working area. Our model-derived source region tritium concentrations agreed well with annual mean station values. Moisture that originated from continental Europe and the Atlantic Ocean was most distinct regarding tritium concentrations with values up to 8.8 TU (tritium units) and near 0 TU, respectively. The seasonality of tritium values ranged from 1.6 TU in January to 10.1 TU in May, and they exhibited well-known elevated concentrations in spring and early summer due to increased stratosphere–troposphere exchange. However, this pattern was interrupted by extreme events. The average altitude of trajectories was correlated with the tritium concentrations in precipitation, especially in spring and early summer and if outlier values of extreme tritium concentrations were excluded. However, in combination with the trajectory information, these outlier values proved to be valuable for improving the comprehension of tritium movement in the atmosphere. Our work shows how event-based tritium research can advance the understanding of its distribution in the atmosphere.

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.