We report the magnetic and superconducting properties of locally noncentrosymmetric SrPtAs obtained by muon-spin-rotation/relaxation (µSR) measurements. Zero-field µSR reveals the occurrence of small spontaneous static magnetic fields with the onset of superconductivity. This finding suggests that the superconducting state of SrPtAs breaks time-reversal symmetry. The superfluid density as determined by transverse field µSR is nearly flat approaching T = 0 K proving the absence of extended nodes in the gap function. By symmetry, several superconducting states supporting time-reversal symmetry breaking in SrPtAs are allowed. Out of these, a dominantly d + id (chiral d-wave) order parameter is most consistent with our experimental data. Transition metal pnictides have attracted considerable scientific interest as they present the second largest family of superconductors after the cuprates [1]. All superconductors of this family share one common structural feature: superconductivity takes place in a square lattice formed by the transition metal elements. Very recently superconductivity with a T c of 2.4 K has been discovered in SrPtAs [2], which has a unique and attractive structural feature: It crystallizes in a hexagonal structure with weakly coupled PtAs layers forming a honeycomb lattice. SrPtAs supports three pairs of split Fermi surfaces, two of which are hole-like and centered around the Γ-point with a cylindrical shape extended along the k z direction and together host only about 30% of the density of states. The remaining 70% of the density of states are hosted by the third pair of split Fermi surfaces that is electron-like, centered around the K and K ′

The family of iron arsenide superconductors is expanded by the new iron platinum compounds (CaFe1−xPtxAs10)Pt4−yAs8 with novel crystal structures. Layers of FeAs4/4 tetrahedra and of nearly planar PtAs4/2 squares with (As2)4− dumbbells are stacked in different ways, resulting in polytypes with triclinic or tetragonal symmetry. Superconductivity up to 35 K is induced either by Pt doping of the Fe site or by electron transfer from PtAs to FeAs layers.

The role of different negatively charged layers in Ca 10 (Fe 1−x Pt x As) 10 (Pt The recently discovered compounds Ca10(Fe1−xPtxAs)10(Pt3+yAs8) exhibit superconductivity up to 38 K, and contain iron arsenide (FeAs) and platinum arsenide (Pt3+yAs8) layers separated by layers of Ca atoms. We show that high Tc's above 15 K only emerge if the iron-arsenide layers are at most free of platinum-substitution (x → 0) in contrast to recent reports. In fact Pt-substitution is detrimental to higher Tc, which increases up to 38 K only by charge doping of pure FeAs layers. We point out, that two different negatively charged layers [(FeAs)10] n− and (Pt3+yAs8) m− compete for the electrons provided by the Ca 2+ -ions, which is unique in the field of iron-based superconductors. In the parent compound Ca10(FeAs)10(Pt3As8), no excess charge dopes the FeAs-layer, and superconductivity has to be induced by Pt-substitution, albeit below 15 K. In contrast, the additional Pt-atom in the Pt4As8 layer shifts the charge balance between the layers equivalent to charge doping by 0.2 electrons per FeAs. Only in this case Tc raises to 38 K, but decreases again if additionally platinum is substituted for iron. This charge doping scenario is supported by our discovery of superconductivity at 30 K in the electron-doped La-1038 compound (Ca0.8La0.2)10(FeAs)10(Pt3As8) without significant Pt-substitution.

Radical‐mediated hydrothiolation of enoses was studied as a stereoselective method for synthesizing challenging oligosaccharide structures. Three types of glycals were reacted with various thiols using UV irradiation at the temperature range of rt to −120 °C, producing 39 thioglycosides up to tetrasaccharide. Cooling always proved to be beneficial to the efficacy, −80 °C being the optimal temperature in most cases. The different conformational preferences of the intermediate carbon‐centered radicals were crucial in the stereoselectivity of the reactions. More information can be found in the Full Paper by A. Borbás et al. on page 14555.

We report the structural and magnetic phase transitions of triclinic Ca10(FeAs)10(Pt3As8), which is the parent compound of the 1038-type iron-arsenide superconductors. High-resolution x-ray diffraction reveals splitting of the in-plane (a,b) lattice parameters at T(s) ≈ 120 K. Platinum-doping weakens the distortion and shifts the transition temperature to 80 K in Ca10(Fe(1-x)Pt(x)As)10(Pt3As8) with x = 0.03. μSR experiments show the onset of magnetic order near T and a broad magnetic phase transition. The structural transition involves no reduction of the space group symmetry in contrast to the other parent compounds of iron-arsenide superconductors; nevertheless the local fourfold symmetry of the FeAs-layers in Ca10(FeAs)10(Pt3As8) is broken.