A large number of particle detectors employ liquid argon as their target material owing to its high scintillation yield and its ability to drift ionization charge over large distances. Scintillation light from argon is peaked at 128 nm and a wavelength shifter is required for its efficient detection. In this work, we directly compare the light yield achieved in two identical liquid argon chambers, one of which is equipped with polyethylene naphthalate (PEN) and the other with tetraphenyl butadiene (TPB) wavelength shifter. Both chambers are lined with enhanced specular reflectors and instrumented with SiPMs with a coverage fraction of approximately 1%, which represents a geometry comparable to the future large scale detectors. We measured the light yield of the PEN chamber to be  39.4$$\,\pm \,$$ ± 0.4(stat)$$\,\pm \,$$ ± 1.9(syst)% of the yield of the TPB chamber. Using a Monte Carlo simulation this result is used to extract the wavelength shifting efficiency of PEN relative to TPB equal to 47.2$$\,\pm \,$$ ± 5.7%. This result paves the way for the use of easily available PEN foils as a wavelength shifter, which can substantially simplify the construction of future liquid argon detectors.

Exfoliated g-C3N4 is a well-known semiconductor utilized in heterogenous photocatalysis and water splitting. An improvement in light harvesting and separation of photogenerated charge carriers may be obtained by polymer doping with sulfur. In this work, we incorporate sulfur into the polymer chain by chemical polymerization of trithiocyanuric acid (C3N3S3H3) to obtain C3N3S3. The XRD measurements and TEM images indicated that C3N3S3, in contrast to g-C3N4, does not exist in the form of a graphitic structure and is not exfoliated into thin lamellas. However, both polymers have similar optical properties and positions of the conduction and valence bands. The comparative studies of electrochemical oxygen reduction and hydrogen evolution indicated that the overpotentials for the two processes were smaller for C3N3S3 than for g-C3N4. The RDE experiments in the oxygen-saturated solutions of 0.1 M NaOH have shown that O2 is electrochemically reduced via the serial pathway with two electrons involved in the first step. The spectroscopic experiments using NBT demonstrated that both polymers reveal high activity in the photocatalytic reduction of oxygen to superoxide anion radical by the photogenerated electrons.

A new concept for the simultaneous detection of primary and secondary scintillation in time projection chambers is proposed. Its core element is a type of very-thick GEM structure supplied with transparent electrodes and machined from a polyethylene naphthalate plate, a natural wavelength shifter. Such a device has good prospects for scalability and, by virtue of its genuine optical properties, it can improve on the light collection efficiency, energy threshold and resolution of conventional micropattern gas detectors. This, together with the intrinsic radiopurity of its constituting elements, offers advantages for noble gas and liquid based time projection chambers, used for dark matter searches and neutrino experiments. Production, optical and electrical characterization, and first measurements performed with the new device are reported.

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