This study was aimed at comparing selected properties of starch citrate obtained from native or retrogrades of potato starch at various temperatures (100, 130 or 160°C) and at various doses of reactant (10, 20 or 40 g per 100 g). Higher susceptibility to esterification was demonstrated for retrograded starch, whereas the degree of esterification of the produced esters varied considerably (1.4 to 10.0 g per 100 g preparation) and was increasing along with increasing roasting temperature and dose of citric acid. The process of pasting occurred only in the esters obtained at a temperature of 100°C, which resulted in a significant decrease in swelling power and solubility in water of the citrates produced at higher temperatures. The resultant starch citrates were characterised by significant resistance to amylolysis (ranging from 22 to 100 g per 100 g). There was observed an increase in starch resistance along with the increase in the acid dose and roasting temperature. All analysed properties of starch citrates were not correlated with the degree of esterification, but appeared to depend on the roasting, which may point to a significant effect of this factor on the mechanism of starch cross-linking with citric acid.
Extrudates used in the study were prepared on the base of cornmeal (100%)control, which was in 10, 30 and 50% replaced by defatted seeds of blackcurrant, which were a by-product of supercritical fluid extraction, used for oil production. The aim of the study was to check the influence of the level of defatted blackcurrant seeds, on texture and chemical composition of the obtained extrudates. Special attention was paid to pro-health constituents, i.e., dietary fiber, polyphenols, flavonoids and anthocyanins. The addition of defatted seeds resulted in an increase of polyphenol content, and antioxidant activity, and the rise in the level of flavonoids and soluble dietary fiber as compared with control. The enrichment of extrudates in pro-health components, as well as improvement of sensory score, suggests that 10% addition of defatted blackcurrant seeds is a suitable level for preparation of extruded fruit-cereal snacks.
PRACTICAL APPLICATIONSThe study demonstrates that defatted blackcurrant seeds could be a good, natural source of bioactive components in cereal snacks produced by extrusion. The suggested level of this component, optimal from sensory and dietary point of view, is 10%.
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