The conditions for photocatalytic degradation of ethylenediaminetetraacetic acid (EDTA) in aqueous solution with Fe-doped titanium dioxide (TiO2) were optimized. The degradation efficiencies with Fe-doped TiO2 were better, compared with those obtained with bare TiO2 and Pt-doped TiO2. The effect of various experimental factors, such as photocatalytic dosage, temperature, solution pH and light intensity on the photocatalytic degradation of EDTA by Fe-doped TiO2 was investigated. The photocatalytic degradation treatment for the wastewater containing EDTA is simple, easy handling and low cost.

In recent years, photocatalysts have been used in various fields, and are particularly attracting attention in the fields of environment, medicine, and agriculture. A large number of catalytic active sites are required to produce a more efficient photocatalyst, and for that purpose, a large specific surface area is desired. Therefore, in this study, in order to develop a highly active photocatalytic material, the outer diameter of titanium oxide nanotubes was controlled by a template synthesis method using carbon nanotubes with different outer diameters to increase the specific surface area. Characterization was carried out by using diffent analytical instruments such as UV-Spectrophotomoter, XRD, SEM, TEM, BET. Results show using titanium oxide nanotubes with a smaller outer diameter tended to have higher photocatalytic activity (almost complete degradation was obtained when 10-20nm was used).