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The ferromagnetic interaction was observed in a conducting ion-radical salt of a TTF-based cross-cyclophane type dimeric donor.

A novel dimeric TTF derivative (1) of a cross-cyclophane type was prepared through an intramolecular coupling of a cyclic tetramer of alkylated dmit. The crystal structure of 1·TCNQ indicates a unique sheet structure of 1 through face-to-face and two types of side-by-side interactions. Cyclic voltammetric measurement of 1 suggests the presence of intramolecular interaction between two donor units.

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