Autonomous recovery for original states is a distinctive
property
in living organisms that stimulates the development of artificial
materials with unprecedented responsiveness and autonomy because such
bioinspired functions can be potentially applied to biomedical materials
and devices. Therefore, excellent responsivity to external subtle
stimuli is highly desirable. We designed a poly(NIPAM-co-CD-co-DBD) bearing a β-cyclodextrin (CD)
host and dimethylaminosulfonyl-2,1,3-benzoxadiazole (DBD) guest to
realize highly responsive temperature-induced autonomous reswelling
due to interchain cross-linking of the polymer chains via CD–DBD
complexation, though a previous poly(NIPAM-co-CD)
needs stronger temperature stimuli for its autonomous reswelling.
Density functional theory calculations indicate a promising steric
conformation of the CD–DBD complex for the autonomous reswelling.
Thus, a small temperature change, heating with 0.5 °C steps,
can lead to repeated autonomous reswelling. Furthermore, the autonomous
reswelling was successfully detected based on the fluorescent character
of DBD, which proved the capability for visual detection of the autonomous
reswelling.
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