We present an analytically solvable theory of Bose–Einstein condensation (BEC) in thin film geometries. Analytical closed-form expressions for the critical temperature are obtained in both the low-to-moderate confinement regime (where the film thickness L is in the order of microns) as well as in the strong confinement regime where the thickness is in the order of few nanometers or lower. The possibility of high-temperature BEC is predicted in the strong confinement limit, with a square-root divergence of the critical temperature T c ∼ L −1/2. For cold Bose gases, this implies an enhancement up to two orders of magnitude in T c for films on the nanometer scale. Analytical predictions are also obtained for the heat capacity and the condensate fraction. A new law for the heat capacity of the condensate, i.e. C ∼ T 2, is predicted for nano-scale films, which implies a different λ-point behavior with respect to bulk systems, while the condensate fraction is predicted to follow a [ 1 − ( T / T c ) 2 ] law.
We present an analytically solvable theory of Bardeen-Cooper-Schrieffer-type superconductivity in good metals which are confined along one of the three spatial directions, such as thin films. Closed-form expressions for the dependence of the superconducting critical temperature [Formula: see text] as a function of the confinement size [Formula: see text] are obtained, in quantitative agreement with experimental data with no adjustable parameters. Upon increasing the confinement, a crossover from a spherical Fermi surface, which contains two growing hollow spheres corresponding to states forbidden by confinement, to a strongly deformed Fermi surface, is predicted. This crossover represents a new topological transition, driven by confinement, between two Fermi surfaces belonging to two different homotopy classes. This topological transition provides a mechanistic explanation of the commonly observed non-monotonic dependence of [Formula: see text] upon film thickness with a maximum which, according to our theory, coincides with the topological transition.
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