Shape memory polymers (SMPs) are materials capable of changing their structural configuration from a fixed shape to a temporary shape, and vice versa when subjected to a thermal stimulus. The present work has investigated the 3D printing process of a shape memory polymer (SMP)-based polyurethane using a material extrusion technology. Here, SMP pellets were fed into a printing unit, and actuating coupons were manufactured. In contrast to the conventional film-casting manufacturing processes of SMPs, the use of 3D printing allows the production of complex parts for smart electronics and morphing structures. In the present work, the memory performance of the actuating structure was investigated, and their fundamental recovery and mechanical properties were characterized. The preliminary results show that the assembled structures were able to recover their original conformation following a thermal input. The printed parts were also stamped with a QR code on the surface to include an unclonable pattern for addressing counterfeit features. The stamped coupons were subjected to a deformation-recovery shape process, and it was observed that the QR code was recognized after the parts returned to their original shape. The combination of shape memory effect with authentication features allows for a new dimension of counterfeit thwarting. The 3D-printed SMP parts in this work were also combined with shape memory alloys to create a smart actuator to act as a two-way switch to control data collection of a microcontroller.

Additive manufacturing has allowed for the production of complex and mass customized geometries, but often at the expense of mechanical performance, a penalty which can be in part mitigated with the fabrication of composite parts. Thermoplastic structures fabricated with material extrusion additive manufacturing stand to be improved in terms of fracture toughness with the integration of continuous fibers. The present research program has investigated the production of a continuously reinforced filament to be used in open-source fused filament fabrication systems. Three different volume fractions of Kevlar fibers were incorporated into a polylactic acid (PLA) thermoplastic filament. It was observed that a 20% fiber volume fraction resulted in a doubling of the tensile strength relative to the unreinforced PLA parts. High-velocity impact tests were also performed on the reinforced printed thermoplastic material, and it was observed that the composite with the highest fiber volume fraction provided an impact energy resistance improved by a factor of four, relative to the plain PLA. The reinforced fibers have shown to restrain the penetration of the projectile at velocities similar to those that perforated the unreinforced PLA. The present work has demonstrated the production of printed composites without the need of modifying the extruding systems of a commercial 3D printer. This approach could represent an alternate and feasible process for producing continuously reinforced 3D-printed thermoplastic parts with utility for high-velocity impact applications.

Shape memory polymers (SMPs) are smart materials that can respond to certain thermal, chemical or electrical stimuli by inducing a structural conformation change into a temporary shape. In this work, a 3D printing process based on a Vat Photo-polymerization of a shape memory polymer (SMP) was investigated to produce customized smart and complex morphable antennas. The mechanical and material properties were examined through a tensile, flexural and rheological testing for different polymer mixture ratios. It was observed that the combination of 20% of an elastomeric resin in a thermoset UV system yields the highest shape recovery performance. The fabrication process of the antenna was based on the incorporation of a conductive material. The approach involved the inclusion of a thin copper electroplating technique. The radiofrequency performance of the fabricated antenna was examined by a vector network analyzer (VNA) and it was observed that a thermal stimulus was capable of inducing a conformal shape on the antenna, resulting in a multi-radio frequency morphing system. The antenna performance was simulated in Ansys HFSS.