Topological insulators are a striking example of materials in which topological invariants are manifested in robustness against perturbations [1,2]. Their most prominent feature is the emergence of topological edge states with reduced dimension at the boundary between areas with distinct topological invariants. The observable physical effect is unidirectional robust transport, unaffected by defects or disorder. Topological insulators were originally observed in the integer quantum Hall effect [3], and subsequently suggested [4-6] and observed [7] even in the absence of magnetic field. These were fermionic systems of correlated electrons. However, during the past decade the concepts of topological physics have been introduced into numerous fields beyond condensed matter, ranging from microwaves [8,9] and photonic systems [10-12] to cold atoms [13,14], acoustics [15,16] and even mechanics [17,18]. Recently, topological insulators were proposed [19-21] in exciton-polariton systems organized as honeycomb (graphene-like) lattices, under the influence of a magnetic field. Topological phenomena in polaritons are fundamentally different from all topological effects demonstrated experimentally thus far: exciton-polaritons are part-light part-matter quasiparticles emerging from the strong coupling of quantum well excitons and cavity photons [22]. Here, we demonstrate experimentally the first exciton-polariton topological insulator. This constitutes the first symbiotic light-matter topological insulators. Our polariton lattice is excited non-resonantly, and the chiral topological polariton edge mode is populated by a polariton condensation mechanism. We use scanning imaging techniques in real-space and in Fourier-space to measure photoluminescence, and demonstrate that the topological edge mode avoids defects, and that the propagation direction of the mode can be reversed by inverting the applied magnetic field. Our exciton-polariton topological insulator paves the way for a variety of new topological phenomena, as they involve light-matter interaction, gain, and perhaps most importantly -exciton-polaritons interact with one another as a nonlinear many-body system.Microcavity exciton-polaritons (polaritons) are composite bosons originating from the strong coupling of quantum well excitons to microcavity photons. While the excitonic fraction provides a strong non-linearity, the photonic part results in a low effective mass, allowing the formation of a driven-dissipative Bose-Einstein condensate [23,24] and a superfluid phase [25], making polaritons being referred to as "quantum fluids of light" [26]. For the epitaxially well-controlled III-V semiconductor material system, a variety of techniques are available to micropattern such cavities in order to precisely engineer the potential landscapes of polaritons [27]. With the recent advances of bringing topological effects to the realms of photonics [8][9][10][11][12]28], several avenues to realize topological edge propagation with polaritons have been suggested [19][20][21], wi...
The work presents microscopic observations of heterogeneous ice nucleation from experiments conducted inside an environmental scanning electron microscope. Observations of ice formation on kaolinite particles demonstrate that ice preferentially nucleates at the edges of the stacked platelets, rather than on the basal planes. This platform is applied for directly detecting and tracking ice nucleating particles in ambient aerosol samples and is complemented by micro-spectroscopic chemical imaging. This technique opens a path to new physical chemistry studies of ice formation in atmospheric science, cryobiology, and material science.www.rsc.org/pccp Heterogeneous ice nucleation is a physical chemistry process of critical relevance to a range of topics in the fundamental and applied sciences and technologies. Heterogeneous ice nucleation remains insufficiently understood, partially due to the lack of experimental methods capable of obtaining in situ microscopic details of ice formation over nucleating substrates or particles. We present microscopic observations of ice nucleation events on kaolinite particles at the nanoscale and demonstrate the capability of direct tracking and micro-spectroscopic characterization of individual ice nucleating particles (INPs) in an authentic atmospheric sample. This approach utilizes a custom-built ice nucleation cell, interfaced with an Environmental Scanning Electron Microscope (IN-ESEM platform) operated at temperatures and relative humidities relevant for heterogeneous ice nucleation. The IN-ESEM platform allows dynamic observations of individual ice formation events over particles in isobaric and isothermal experiments. Isothermal experiments on individual kaolinite particles demonstrate that ice crystals preferably nucleate at the edges of the stacked kaolinite platelets, rather than on their basal planes.These experimental observations of the location of ice nucleation provide direct information for further theoretical chemistry predictions of ice formation on kaolinite.
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