Dye-sensitized solar cells (DSSCs) were fabricated using a quasialigned one-dimensional zinc oxide (ZnO) nanostructure. The ZnO nanostructures were grown on indium tin oxide (ITO) coated glass substrate via a thermal chemical vapor deposition (CVD). It has been considered that thermal CVD is not suitable for the growth of ZnO nanostructure on ITO/glass due to the high processing temperature. However, we have demonstrated that a densely populated ZnO nanostructure can be prepared on ITO/glass substrate by a double-source double-tube CVD process. The power conversion efficiency of our device is 0.6%.

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A novel ionic liquid, 3-{[{4-[((carbamoyl)amino)ethyl methacrylate]butyl} ((carbamoyl)amino)ethyl methacrylate]propyl}-1-ethenyl-1H-imidazol-3-ium bromide (CCPEimBr) functionalized with vinyl, amino, and methacrylate groups, was synthesized and characterized with H NMR, FTIR, and HPLC-MS techniques. CCPEimBr was adopted as the functional monomer to prepare a molecularly imprinted polymerized ionic liquid hydrogel film on a glassy carbon electrode surface for human epididymis protein 4 (HE4) sensing. Gold nanoparticles (AuNPs) and ZnCdHgSe QDs were incorporated into the imprinted film as photo-electric active materials. The photocurrent response was measured to investigate the sensing performance of the imprinted sensors toward HE4. The imprinted photo-electrochemical sensor shows excellent selectivity, sensitivity, stability, and accuracy for HE4 determination. Experimental conditions including incubation time and pH value for determining HE4 were optimized in this study. The photocurrent variation (ΔI) decreased with increasing HE4 concentration (c), and it was linearly proportional to c varied from 25 pg mL to 4.0 ng mL. The detection limit of the imprinted sensor for determining HE4 was estimated to be 15.4 pg mL (S/N = 3). The imprinted photo-electrochemical sensor was used to determine HE4 in human serum samples accurately.

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