No abstract

Bamboo strips extracted from Phyllostachys viridiglaucescens, grown in Europe, were analysed to assess their thermal and mechanical properties for composites application. Thermal stability of the European bamboo was studied by Thermogravimetric Analysis (TGA) and compared to the one of species grown in Oceania. An evolution of the chemical composition along the radial direction of the Phyllostachys bamboo was identified by TGA. The inner part of culms shows a higher proportion of hemicelluloses, while the percentage of crystalline cellulose is higher in the outer portion. This evolution of the composition was used to interpret the original data recorded by Dynamic Mechanical Analysis (DMA) of the strips. Glassy tensile modulus founded by DMA increases from the inner part of the culm (6.8 GPa) to the outer part (9.9 GPa). The variation of the cellulose content along the radius of the bamboo culm is related to this increase and shows a good correlation with thermal behaviour. The dynamic relaxations in the shear mode reveal the existence of two secondary relaxation modes sensitive to water. In the order of increasing temperatures, they have been assigned to the mobility of methylol groups and to heterogeneities of the polymeric matrix. By combining Differential Scanning Calorimetry (DSC) and DMA, the response of the viscoelastic transition of bamboo strips, at 210 °C, was evidenced for the first time. Bamboo strips behave as a unidirectional composite reinforced by technical fibres; its particularly high shear glassy modulus (2.3 GPa) deserves to be emphasised.

A biobased composite was generated from bamboo fibers (BF) and a polyamide 11 (PA11) matrix. In order to fulfill security requirements, a PA11 already containing a flame retardant (FR) was chosen: This matrix is referred as PA11-FR. In this work, the effects of flame retardant (melamine cyanurate) on the composite properties were considered. In the calorimetric study, the glass transition and melting temperatures of PA11-FR were the same as those of PA11. The melamine cyanurate (MC) had no influence on these parameters. Thermogravimetric analysis revealed that PA11-FR was less stable than PA11. The presence of MC facilitated thermal decomposition regardless of the analysis atmosphere used. It is important to note that the presence of FR did not influence processing conditions (especially the viscosity parameter) for the biosourced composite. Continuous BF-reinforced PA 11-FR composites, single ply, with 60% of fibers were processed and analyzed using dynamic mechanical analysis. In shear mode, comparative data recorded for BF/PA11-FR composite and the PA11-FR matrix demonstrated that the shear glassy modulus was significantly improved: multiplied by a factor of 1.6 due to the presence of fibers. This result reflected hydrogen bonding between reinforcing fibers and the matrix, resulting in a significant transfer of stress. In tensile mode, the conservative modulus of BF/PA11-FR reached E’ = 8.91 GPa. Upon BF introduction, the matrix tensile modulus was multiplied by 5.7. It can be compared with values of a single bamboo fiber recorded under the same experimental conditions: 31.58 GPa. The difference is partly explained by the elementary fibers’ lack of alignment in the composite.