Oxidation of n-octane was carried out in a stationary reactor using immobilized manganese nanoparticles in various mass percentages (5 and 10 wt.%) on poly(4-vinylpyridine). It was found that manganese-containing catalysts immobilized in polymer are more active in the oxidation of n-octane than similar homogeneous catalysts. A kinetic model and an equation for calculating the oxidation of n-octane in the presence of a manganese-polymer catalyst were chosen for the calculation. Taking into account the kinetic model, the velocity constant of the specified process is calculated. A high conversion in the oxidation reaction of n-octane with molecular oxygen was obtained
Metal-polymer catalysts in the reaction of hydrogenation of benzene have been studied. Salts of nickel, palladium, and H2PtCl6·6H2O were used as metals, which were deposited on polymer carriers, in particular, on polyethylenepolyamine, poly-2-methyl-5-vinylpyridine, styrene copolymer with maleic anhyd¬ride, and poly-4-vinylpyridine. A number of polymer complexes were also synthesized, tuned to benzene hydrogenation products and cross-linked with N,N'-methylenebisacrylamide, a crosslinking agent. The temperature of the hydrogenation reaction was controlled within 20–600C. Hydrogenation was carried out in an autoclave. It has been established that complexes based on platinum and poly-4-vinylpyridine lead to a high yield of the product of incomplete hydrogenation of benzene, cyclohexene. Also, it has been established that the Pt-poly-2-methyl-5-vinylpyridine complex tuned to benzene and cyclohexene exhibits a higher catalytic activity
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.