Rare earth based intermetallics, SmScGe and NdScGe, are shown to exhibit near zero net magnetization with substitutions of 6 to 9 atomic % of Nd and 25 atomic % of Gd, respectively. The notion of magnetic compensation in them is also elucidated by the crossover of 'zero magnetization' axis at low magnetic fields (< 10 3 Oe) and field-induced reversal in the orientation of the magnetic moments of the dissimilar rare earth ions at higher magnetic fields. These magnetically ordered materials with 'no-net' magnetization and appreciable conduction electron polarization display an attribute of an exchange bias field, which can be tuned. The attractively high magnetic ordering temperatures of ~ 270 K, underscore the importance of these materials for potential applications in spintronics.
A compensated magnetic state in an ideally homogeneous system with long range magnetic order is characterized by a net zero magnetization (M) throughout the sample (macroscopic). In the pristine state of the sample (i.e. with no external field, H = 0), this implies that at the magnetic compensation temperature (Tcomp) we must have M = 0 at H = 0 irrespective of any thermal and magnetic history of the sample and any underlying physics. This simple fact voids the usual identification (and interpretation) of M-H loop parameters at and in the vicinity of magnetic compensation temperature, specifically the coercivity, the remanence, and the exchange bias characteristics. The physics of coercivity and exchange bias continues to be fully relevant, but its manifestation in an M-H loop would get camouflaged at (and near) a magnetic compensation because [Formula: see text] at H = 0. We present an experimental elucidation of the above premise through a case study in the spin ferromagnetic Sm1 - xGdxAl2 alloys [x = 0.01-0.06], where the specimens with x ≤ 0.03 show compensation below the Curie temperature Tc, while those with x ≥ 0.03 have rather small magnetization due to near cancellation of opposing contributions, but are otherwise devoid of compensation. The experiments comprised low field (near zero) as well as high field (70 kOe) magnetization measurements from the paramagnetic state down to 5 K in the ordered regime (Tc ∼ 125 K) and isothermal M-H loop studies on the remnant magnetic state of polycrystalline samples.
Global shortages of N95 respirators have led to an urgent need of N95 decontamination and reuse methods that are scientifically validated and available world-wide. Although several large scale decontamination methods have been proposed (hydrogen peroxide vapor, UV-C); many of them are not applicable in remote and low-resource settings. Heat with humidity has been demonstrated as a promising decontamination approach, but care must be taken when implementing this method at a grassroots level. Here we present a simple, scalable method to provide controlled humidity and temperature for individual N95 respirators which is easily applicable in low-resource settings. N95 respirators were subjected to moist heat (>50% relative humidity, 65–80°C temperature) for over 30 minutes by placing them in a sealed container immersed in water that had been brought to a rolling boil and removed from heat, and then allowing the containers to sit for over 45 minutes. Filtration efficiency of 0.3–4.99 μm incense particles remained above 97% after 5 treatment cycles across all particle size sub-ranges. This method was then repeated at a higher ambient temperature and humidity in Mumbai, using standard utensils commonly found in South Asia. Similar temperature and humidity profiles were achieved with no degradation in filtration efficiencies after 6 cycles. Higher temperatures (>70°C) and longer treatment times (>40 minutes) were obtained by insulating the outer vessel. We also showed that the same method can be applied for the decontamination of surgical masks. This simple yet reliable method can be performed even without electricity access using any heat source to boil water, from open-flame stoves to solar heating, and provides a low-cost route for N95 decontamination globally applicable in resource-constrained settings.
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