We present an extended synchrotron x-ray scattering study of the structure of thin manganite films grown on SrTiO3(001) substrates and reveal a new kind of misfit strain relaxation process which exploits twinning to adjust lattice mismatch. We show that this relaxation mechanism emerges in thin films as one-dimensional twinning waves which freeze out into a twin domain pattern as the manganite film continues to grow. A quantitative microscopic model which uses a matrix formalism is able to reproduce all x-ray features and provides a detailed insight into this novel relaxation mechanism. We further demonstrate how this twin angle pattern affects the transport properties in these functional films.
In order to advance consistent lightweight construction principles in automotive and mechanical engineering, support frame construction made from high-performance materials is becoming more commonplace. These consist of complexly structured nodular connection elements. The required connection elements have not yet been produced satisfactorily. The developed node element structures in this paper are produced on a shuttle weaving loom by flattening and weaving them as multi-surface woven fabrics. The development of the woven concept for the realization of node element structures is based on the fragmentation of the individual sub-elements. The goal of this research is development of a flexible technology for weaving fabrics and intended for the integral realization of woven nodular semi-finished products with complex geometries and connections, which are to be used to connect Fiber-reinforced Plastic components in support frame structures.
X-ray scattering experiments have demonstrated that for thin films (100 Å to 500 Å) of La0.9Sr0.1MnO3 epitaxially grown on SrTiO3 (100) substrates, the accommodation of the lattice mismatch between film and substrate gives rise to a modulated structure. The nonbulk-like structural properties of these thin films are the origin of anomalies in the electronic and magnetic behavior. Studies of the lattice as a function of temperature clearly reveal a magnetostrictive effect close to the Curie temperature. For thicker films the strain relief mechanism is replaced by formation of coherent microtwins and some of the bulk properties are recovered, but some differences are still observed.
c EDP Sciences( 5 )To calculate the lattice mismatch we have used the film pseudocubic in-plane lattice constant (a + b)/2 √ 2.
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