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Synthesis, thermal, spectral, electrochemical, and magnetic properties of transition metal complexes of 2-bromo-3hydroxynaphthalene-1,4-dione(abbreviated as L) are discussed. The complexes viz, [Zn(L)2(H2O)2]; ZnL, [Cu(L)2(H2O)2]; CuL, [Ni(L)2(H2O)2]; NiL, [Co(L)2(H2O)2]; CoL, are resulted from the reactions of L with respective metal chlorides in methanol. The carbonyl frequency (1633 cm -1 ) of the ligand remains the same in ZnL, whereas it is observed at a higher wavenumber (17 cm -1 ) in CuL and lower wavenumber (3 cm -1 ) in NiL and CoL. The thermal decomposition of the complexes was studied by thermogravimetry. Powder X-ray diffraction studies further analyzed the respective metal oxide formed in TG studies. Redox potentials of all complexes are determined by cyclic voltammetry studies. It is difficult to reduce or oxidize the ligand after complexation. The frozen solution (DMSO) spectrum (133 K) of CuL shows four 63 Cu hyperfine lines in the g║region with A║ = ~155 G in CuL. The ligand, as well as all-metal complexes, showed considerable antibacterial activity against six strains viz.