Discovery of plasmon resonance and negative permittivity in carbon allotropes at much lower frequencies than those of metals has evoked interest to develop random metacomposites by suitable means of addition of these dispersoids in an overall dielectric matrix. Random metacomposites have always the advantage for their easy preparation techniques over those of their regular arrayed artificial counterpart. However, thermal management during the heat generation by electromagnetic attenuation in metamaterials is not yet studied well. The present communication discusses the dielectric permittivities and loss parameters of aluminum nitride−single-wall carbon nanotube (AlN−SWCNT) composites considering high thermal conductivities of both materials. The composites are dense and have been prepared by a standard powder technological method using hot pressing at 1850 °C under a nitrogen atmosphere. Increase in the negative permittivity value with SWCNT concentration (1, 3, and 6 vol %) in the composites had been observed at low frequencies. Characterization of the materials with Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and microstructure analysis by scanning and transmission electron microscopy (TEM) revealed the survivability of the SWCNTs and the nature of the matrix−filler interface. Plasmonic resonance following Drude's law could be observed at much lower plasma frequencies than that of pure SWCNT and for very little SWCNT addition. Exhibition of the negative permittivity has been explained with relation to the microstructure of the composites observed from field emission scanning electron micrographs (FESEM), TEM images, and the equivalent circuit model. High energy conversion efficiency is expected in these composites due to the possession of dual functionalities like high thermal conductivity as well as high negative permittivity, which should ensure the application of these materials in wave filter, cloaking device, supercapacitors, and wireless communication.
In the present investigation, WC-10Co-4Cr coating was deposited by high velocity air-fuel (HVAF) process on CA6NM hydro turbine steel. A detailed microstructural and phase compositional study was carried out on the coating. Mechanical properties of the coating were also evaluated. WC-10Co-4Cr coating showed a homogeneous, well-bonded structure with low porosity, which is mainly attributed to less decarburization of WC. Erosion resistance of the coating was evaluated by air jet erosion tester at three different impingement angles (30[Formula: see text], 60[Formula: see text] and 90[Formula: see text]) for 35 and 70[Formula: see text]m/s impact velocities. The FESEM micrographs were taken, before and after erosion tests, to determine the erosion mechanism. The test results revealed that the coating protects the substrate at 30[Formula: see text], 60[Formula: see text] and 90[Formula: see text] impingement angles. At 70[Formula: see text]m/s impact velocity, uncoated and coated steel showed higher cumulative volume loss than in the case of 35[Formula: see text]m/s impact velocity. It was observed that uncoated steel showed a ductile behavior during erosion and WC-10Co-4Cr coating showed mixed (ductile and brittle) mode of fracture during erosion.
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