Abstract. Short-lived climate forcers have been proven important both for the climate
and human health. In particular, black carbon (BC) is an important climate
forcer both as an aerosol and when deposited on snow and ice surface because
of its strong light absorption. This paper presents measurements of elemental
carbon (EC; a measurement-based definition of BC) in snow collected from
western Siberia and northwestern European Russia during 2014, 2015 and 2016.
The Russian Arctic is of great interest to the scientific community due to
the large uncertainty of emission sources there. We have determined the major
contributing sources of BC in snow in western Siberia and northwestern
European Russia using a Lagrangian atmospheric transport model. For the first
time, we use a recently developed feature that calculates deposition in
backward (so-called retroplume) simulations allowing estimation of the
specific locations of sources that contribute to the deposited mass. EC concentrations in snow from western Siberia and northwestern European
Russia were highly variable depending on the sampling location. Modelled BC
and measured EC were moderately correlated (R=0.53–0.83) and a systematic
region-specific model underestimation was found. The model underestimated
observations by 42 % (RMSE = 49 ng g−1) in 2014, 48 % (RMSE = 37 ng g−1)
in 2015 and 27 % (RMSE = 43 ng g−1) in 2016. For EC
sampled in northwestern European Russia the underestimation by the model was
smaller (fractional bias, FB > −100 %). In this region, the
major sources were transportation activities and domestic combustion in
Finland. When sampling shifted to western Siberia, the model underestimation
was more significant (FB < −100 %). There, the sources included
emissions from gas flaring as a major contributor to snow BC. The accuracy
of the model calculations was also evaluated using two independent datasets
of BC measurements in snow covering the entire Arctic. The model
underestimated BC concentrations in snow especially for samples collected in
springtime.
The mercury concentration levels in the water of aquatic ecosystem of the Northern Dvina River delta are defined. The interrelations of mercury concentrations with physicochemical parameters of the water body, namely with pH, Eh, temperature, salinity, oxygen and organic matter content are studied. The dominant forms of mercury migration and its presence in the water are revealed. Regularities of changes and spatial variability of the mercury concentrations in the estuarine area of the river, peculiarities of mercury compound migration and transformation in the barrier zone of the Northern Dvina River-Dvina Bay of the White Sea are studied.
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