Rare earth elements (REE) are present at low concentrations (hundreds of ppm) in phosphoric acid solutions produced by the leaching of phosphate ores by sulfuric acid. The strongly acidic and complexing nature of this medium, as well as the presence of metallic impurities (including iron and uranium), require the development of a particularly cost effective process for the selective recovery of REE. Compared to the classical but costly solvent extraction, liquid-solid extraction using commercial chelating ion exchange resins could be an interesting alternative. Among the different resins tested in this paper (Tulsion CH-93, Purolite S940, Amberlite IRC-747, Lewatit TP-260, Lewatit VP OC 1026, Monophos, Diphonix,) the aminophosphonic IRC-747, and aminomethylphosphonic TP-260 are the most promising. Both of them present similar performances in terms of maximum sorption capacity estimated to be 1.8 meq/g dry resin and in adsorption kinetics, which appears to be best explained by a moving boundary model controlled by particle diffusion.

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The PACTITER code derives from the PACTOLE code, developed by the CEA for predicting activated corrosion products (ACPs) in PWR primary circuits. The operating conditions, material compositions and water chemistry of the various Primary Heat Transfer Systems (PHTS) of the International Thermonuclear Experimental Reactor (ITER) made mandatory the adaptation of the PACTOLE code.PACTITER was developed on the basis of dedicated experiments, namely devoted to determine copper solubility and stainless steel release in the ITER primary cooling systems conditions, which are rather different from those in PWR (i.e. water chemistry and temperatures). The PACTITER code has been extensively used in support of the ITER Generic Site Safety Report (GSSR) in the field of accident analysis and worker collective dose assessment.