The ceramic flux for submerged arc-surfacing with main component composition MgO (10.0 wt. %)-Al2O3 (25.0 wt. %)-SiO2 (40.0 wt. %)-CaF2 (25.0 wt. %) was prepared in a disk dryer-granulator using a sodium/potassium silicate solution as a binder. X-ray powder diffraction (XRPD) collected at r.t. identified α- phase of quartz, Al2O3, MgO and CaF2 of the initial components in the samples taken after granulation and subsequent annealing at 600 °C. In contrast to the low temperature annealing, anorthite (CaAl2Si2O8) is the main phase in the composition of the samples remelted at 1500 °C and quenched subsequently. Chemical analysis performed by means of scanning electron microscopy with energy-dispersive X-ray spectroscopy analysis (SEM/EDX) detects that the grains of the remelted samples possess the same Ca : Al : Si elemental ratio as anorthite. High temperature X-ray diffraction (HTXRD) was used to examine structural transformation in the solid at 600 °C < T < 1200 °C and stages of thermal evolution of ceramic flux were determined. The ceramic flux melts completely at the temperature above 1350 °C. The intensity pattern of the flux melt was obtained by X-ray diffraction of scattered X-rays at 1450 °C. After calculating the structure factor (SF), the radial distribution function (RDF) was evaluated and used to calculate the structural basicity of the flux melt

Cored wires are used in numerous welding processes with or without external gas or flux shielding. Submerged arc welding (SAW) with cored wires, seamed or seamless, for joining mild and low alloyed steel grades is a technique that has demonstrated clear advantages during the three last decades. Ever since its invention, the SAW process has evolved with one main goal: to combine quality with productivity. With low alloy wires, the benefits have already been clearly demonstrated and widely exploited. However, little has been written on SAW and cladding with cored wires for corrosion or heat resisting applications. Its extension to high alloy compositions brings corresponding benefits and adds some specific and unique features. This paper focuses on consumable specificities and on the quality and productivity features of SAW with CRA (corrosion resistant alloy) cored wires. It describes the potential as well as the limitations of this technique. Cored wires are now used for submerged arc welding of almost all stainless steels ranging from soft martensitic to super-duplex, and for a series of nickel base compositions as well as for cladding cobalt base alloys. Examples of industrial applications with austenitic, duplex, martensitic and heat resisting stainless steels are given to illustrate the potential of the cored wire solution. 13 Ref., 4 Tables , 25 Figures.

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