No abstract

This article presents the results of experimental studies for information support of the hydraulic compartment of the mathematical model of physicochemical iron removal from groundwater. It is experimentally established that the bound water in the deposit significantly exceeds the mineral component (chemical iron) for any waters with the different levels of iron oxidation. The deposit dehydration takes place at its boundary with the liquid phase. As a result, ferrous iron is gradually oxidized and ferric iron transforms from hydroxide forms to oxide forms, which leads to a decrease in the deposit volume and a increase in its density and strength. Further, the coefficient of the deposit hydrodynamic stability is proposed to use to take into account changes in the properties of the deposit that accumulates in the granular medium. It is experimentally determined that the iron amount remaining in the medium after backwashing increases simultaneously with the deposit's age. It will lead to a gradual reduction of the operational dirt capacity of the granular medium and a need to have measures of the filtration properties restoration or to replace the filter medium entirely.

The mathematical model of physicochemical iron removal from groundwater was developed. It consists of three interrelated compartments. The results of the experimental research provide information in support of the first two compartments of the mathematical model. The dependencies for the concentrations of the adsorbed ferrous iron and deposited hydroxide concentrations are obtained as a result of the exact solution of the system of the mass transfer equations for two forms of iron in relation to the inlet surface of the bed. An analysis of the experimental data of the dynamics of the deposit accumulation in a small bed sample was made, using a special application that allowed to select the values of the kinetic coefficients and other model parameters based on these dependencies. We evaluated the autocatalytic effect on the dynamics of iron ferrous and ferric forms. The verification of the mathematical model was carried out involving the experimental data obtained under laboratory and industrial conditions.

No abstract

Mathematical modeling of detachable filtration in the split filter flow mode was carried out using exact and approximate analytical methods. An engineering technique has been developed to determine the duration of filter cycles, based on quality, economic and technical criteria. Determination of rational filter medium height was considered for two materials differed significantly by economic indexes.