Hydrodeoxygenation of isoeugenol was investigated at 200 °C under 3 MPa total pressure in dodecane as a solvent, in hydrogen, over bifunctional Pt‐ and Ir‐modified Beta zeolites and mesoporous materials. As a comparison, Pt and Ir supported on Al2O3, SiO2 and mesoporous MCM‐41 were also tested. The catalysts were characterized by XRD, CO pulse chemisorption, transmission electron microscopy, scanning electron microscopy, nitrogen adsorption and FTIR pyridine adsorption desorption. The results revealed that the most active and selective catalyst was Pt‐H‐Beta‐300, which exhibits the lowest acidity and largest crystal size of Beta zeolite among the studied Pt‐ and Ir‐modified Beta zeolites. Complete conversion of isoeugenol and 89 % selectivity to propylcyclohexane was obtained with this catalyst in 240 min. The overall deoxygenation selectivity was 100 %, giving dialkylated cyclohexanes as the second major product. The catalyst was regenerated, reduced and reused in the hydrodeoxygenation of isoeugenol with almost the same performance as the fresh catalyst. Thermodynamic analyses and kinetic modelling of the data were also performed.
One-pot menthol synthesis in a trickle bed reactor was investigated using Ru/H-beta-300 extrudates without any binder and Pt- and Ru/H-beta-25 extrudates containing 30 wt% bentonite binder using different methods of metal loading on the extrudates.
Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported Mo x C-SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200°C and 300°C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo 2 C-SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.
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