The effect of thermohydrogen treatment and vacuum ion–plasma nitriding on the determination of the volume and surface structure of ball heads made of Ti–6Al–4V alloy was studied. It was found that the submicrocrystalline structure formed in the head during thermohydrogen treatment makes it possible to achieve hardness values of 39–41 units HRC and a surface roughness of 0.02 μm. It was shown that the creation of a modified layer consisting of ε (TiN) and δ (Ti2N) titanium nitrides on the surface of a ball head and the solid interstitial solution of nitrogen in α-titanium makes it possible to completely eliminate material wear when testing for friction on ultra-high-molecular-weight polyethylene. The equivalent analysis was also conducted with a ball head that had been implanted in a human body for 12 years. It was found that the change in the color of the head, from slightly golden after nitriding to metallic, is due to the formation of an oxynitride nanoscale layer on the surface. It was shown that in contrast with films made of titanium oxide, the film developed in this study has high wear resistance.

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A comparative study of the antifriction characteristics of specimens of the VT6 titanium-based alloy subjected to nitriding without preliminary treatment and after hydrogen heat treatment has been carried out. Hydrogen heat treatment that precedes nitriding reduces the coefficient of friction of the nitrided specimens of the VT6 alloy in pair with the 12Kh18N10T stainless steel by 4-9% under dry friction and increases it by ~47% in a working fluid, which is a 0.9% NaCl solution. Hydrogen heat treatment combined with ionplasma nitriding reduces the coefficient of friction in working fluid by ~41%.