Granular nanofibrous carbons (NFCs) with herringbone structure were synthesised by the decomposition of natural gas over Ni/Al 2 O 3 catalysts, and their performance in the selective oxidation of hydrogen sulphide was studied. Samples obtained over pure Ni catalysts are the strongest mechanically and easiest to produce. However, they show low selectivity for sulphur and are unstable during operation. Boiling in nitric acid followed by annealing led to improvements in catalytic stability and a significant increase in the selectivity for sulphur in the direct oxidation of hydrogen sulphide. The addition of large amounts of water vapour to the reaction mixture dramatically improved the selectivity and stability of the NFCs.

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