Biomass is defined as organic matter from living organisms represented in all kingdoms. It is recognized to be an excellent source of proteins, polysaccharides and lipids and, as such, embodies a tailored feedstock for new products and processes to apply in green industries. The industrial processes focused on the valorization of terrestrial biomass are well established, but marine sources still represent an untapped resource. Oceans and seas occupy over 70% of the Earth’s surface and are used intensively in worldwide economies through the fishery industry, as logistical routes, for mining ores and exploitation of fossil fuels, among others. All these activities produce waste. The other source of unused biomass derives from the beach wrack or washed-ashore organic material, especially in highly eutrophicated marine ecosystems. The development of high-added-value products from these side streams has been given priority in recent years due to the detection of a broad range of biopolymers, multiple nutrients and functional compounds that could find applications for human consumption or use in livestock/pet food, pharmaceutical and other industries. This review comprises a broad thematic approach in marine waste valorization, addressing the main achievements in marine biotechnology for advancing the circular economy, ranging from bioremediation applications for pollution treatment to energy and valorization for biomedical applications. It also includes a broad overview of the valorization of side streams in three selected case study areas: Norway, Scotland, and the Baltic Sea.
Gasification is the process converting solid fuels as coal and organic plant matter, or biomass into combustible gas, called syngas. Gasification is a thermal conversion process using carbonaceous fuel, and it differs substantially from other thermal processes such as incineration or pyrolysis. The process can be used with virtually any carbonaceous fuel. It is an endothermic thermal conversion process, with partial oxidation being the dominant feature. Gasification converts various feedstock including waste to a syngas. Instead of producing only heat and electricity, synthesis gas produced by gasification may be transformed into commercial products with higher value as transport fuels, fertilizers, chemicals and even to substitute natural gas. Thermo-chemical conversion of biomass and solid municipal waste is developing as a tool to promote the idea of energy system without fossil fuels to a reality. In municipal solid waste management, gasification does not compete with recycling, moreover it enhances recycling programs. Pre-processing and after-processing must increase the amount of recyclables in the circular economy. Additionally, end of life plastics can serve as an energy feedstock for gasification as otherwise it cannot be sorted out and recycled. There is great potential for application of gasification technology within the biomass waste and solid waste management sector. Industrial self-consumption in the mode of combined heat and power can contribute to sustainable economic development within a circular economy.
Replacing fossil resources with bioresources is one of the promising directions for more environmentally friendly energy production, but the production and processing of biomass generates a large amount of waste with limited use and recycling possibilities. In this respect Hydrothermal Carbonisation (HTC) offers a sustainable and cost-effective solution for disposal and creation of new products from biomass through resource recovery and through climate-neutral process. In this study the impact of biomass type and HTC conditions on the yield and properties of artificial humic substances and hydrochar to achieve carbon capture aim has investigated. A major impact on the yield of HTC products do have the duration and temperature of the treatment, as well as catalyst used (pH of the reaction) and changing the carbonisation conditions it is possible to design the desirable composition of obtained products. During HTC process significant changes of the biomass composition happens resulting in the removal of most labile components. Although the carbon dioxide sorption capacity of hydrochar is relatively low, after activation efficient sorbent (activated carbon) can be obtained, prospective for carbon capture aims.
Global resource limits and increasing demand for non-fossil energy sources have expanded the research on alternative fuels. Among them, algal biomass is designated as a third-generation feedstock with promising opportunities and the capability to be utilized for energy production in the long term. The paper presents the potential for converting beach wrack containing macroalgal biomass into gaseous fuel as a sustainable option for energy production, simultaneously improving the organic waste management that the coastline is facing. Beach wrack collected in the northern Baltic Sea region was converted by gasification technology applicable for carbon-based feedstock thermal recovery, resulting in syngas production as the main product and by-product biochar. Proximate and ultimate analysis, trace and major element quantification, detection of calorific values for macroalgal biomass, and derived biochar and syngas analysis were carried out. A higher heating value for beach wrack was estimated to be relatively low, 5.38 MJ/kg as received (or 14.70 MJ/kg on dry basis), but produced syngas that contained enough high content of CH4 (42%). Due to macroalgal biomass specifics (e.g., high moisture content and sand admixture), an adjusted gasification process, i.e., the combination of thermochemical procedures, such as mild combustion and pyrolytic biomass conversion, might be a better choice for the greater economic value of biowaste valorization.
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