The nanocrystallization behaviour of Al86Ni6Co2Gd3Y2Tb1 amorphous alloy has been studied by X‐ray diffraction methods involving small angle scattering, resistance measurements and differential scanning calorimetry. It has been established that the transformation in amorphous alloy investigated occurs mainly by the growth process at initial state of transformation while at final stage nucleation contributes into formation of nanocomposite structure. In order to describe the nanocrystallization kinetics of the Al‐based glasses the analytical kinetic equations in the frames of Kolmogorov‐Johnson‐Mehl‐Avrami model have been proposed and the effective volume diffusion coefficient values which govern the diffusion‐limited growth nanocrystals have been determined. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing the burden, to Department of Defense, Washington Headquarters Services, Directorate for Information Operations and Reports (0704-0188), 1215 Jefferson Davis Highway, Suite 1204, Arlington, VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. PLEASE DO NOT RETURN YOUR FORM TO THE ABOVE ADDRESS. REPORT DATE (DD-MM-YYYY)05-02-2010 REPORT TYPE Final Report DATES COVERED (From -To)01-Dec-06 -11-Jun-10 TITLE AND SUBTITLE PERFORMING ORGANIZATION REPORT NUMBERN/A SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES)EOARD Unit 4515 BOX 14 APO AE 09421 SPONSOR/MONITOR'S ACRONYM(S) SPONSOR/MONITOR'S REPORT NUMBER(S)STCU 06-8005 DISTRIBUTION/AVAILABILITY STATEMENTApproved for public release; distribution is unlimited. SUPPLEMENTARY NOTES ABSTRACTThis report results from a contract tasking Institute for Metal Physics, NAS of Ukraine as follows: The demands on materials set by aerospace and aircraft manufacturers include the development of alloys possessing high strength-to-weight ratios and capable to withstand high temperature exposures during service. One of the promising classes of materials which may meet these requirements are Al-based alloys with nanocomposite structures formed by partial crystallization of amorphous precursors the strength of which may exceed 1500 MPa. Solution of the problems concerning alloys chemistry and ability to tailor of certain microstructures is of prime importance for the development of new nanostructured materials. The goals of the project are to perform the systematic experimental studies of the effects of alloy composition and thermal prehistory on glassforming ability, thermal stability, crystallization behaviour and mechanical properties of a series binary, ternary and multicomponent Al-based alloys alloyed by transition metals and rare earths as well as to elaborate appropriate theoretical models of nanocrystallization processes. The main factors responsible for nanoscale microstructure formation will be determined from comparison of the experimental data with the model predictions.As a result a series of new Al-based alloys with nanocomposite structure with improved mechanical properties and enhanced thermal stability will be developed and the fundamental basis for the nanostructured alloys design will be created. SUBJECT TERMS
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