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Marine environments are currently subject to strong ecological pressure due to local and global anthropic stressors, such as pollutants and atmospheric inputs, which also cause ocean acidification and warming. These strains can result in biogeochemical cycle variations, environmental pollution, and changes in benthic-pelagic coupling processes. Two new devices, the Amerigo Lander and the Automatic Benthic Chamber (CBA), have been developed to measure the fluxes of dissolved chemical species between sediment and the water column, to assess the biogeochemical cycle and benthic-pelagic coupling alterations due to human activities. The Amerigo Lander can operate in shallow as well as deep water (up to 6000 m), whereas the CBA has been developed for the continental shelf (up to 200 m). The lander can also be used to deploy a range of instruments on the seafloor, to study the benthic ecosystems. The two devices have successfully been tested in a variety of research tasks and environmental impact assessments in shallow and deep waters. Their measured flux data show good agreement and are also consistent with previous data.

A flow injection analyser coupled with a gas diffusion membrane and a conductometric microdetector was adapted for the field analysis of natural concentrations of free dissolved CO2 and dissolved inorganic carbon in natural waters and used in a number of field campaigns for marine water monitoring. The dissolved gaseous CO2 presents naturally, or that generated by acidification of the sample, is separated by diffusion using a hydrophobic semipermeable gas porous membrane, and the permeating gas is incorporated into a stream of deionised water and measured by means of an electrical conductometric microdetector. In order to make the system suitable and easy to use for in-field measurements aboard oceanographic ships, the single components of the analyser were compacted into a robust and easy to use system. The calibration of the system is carried out by using standard solutions of potassium bicarbonate at two concentration ranges. Calibration and sample measurements are carried out inside a temperature-constant chamber at 25 °C and in an inert atmosphere (N2). The detection and quantification limits of the method, evaluated as 3 and 10 times the standard deviation of a series of measurements of the matrix solution were 2.9 and 9.6 μmol/kg of CO2, respectively. Data quality for dissolved inorganic carbon was checked with replicate measurements of a certified reference material (A. Dickson, Scripps Institution of Oceanography, University of California, San Diego), both accuracy and repeatability were -3.3% and 10%, respectively. Optimization, performance qualification of the system and its application in various natural water samples are reported and discussed. In the future, the calibration step will be operated automatically in order to improve the analytical performance and the applicability will be increased in the course of experimental surveys carried out both in marine and freshwater ecosystems. Considering the present stage of development of the method, it can only be applied for studying of the carbon cycle in oxic environments.

<p>To evaluate the anthropogenic impact in surface sediments of the Northern and Central Adriatic Sea, dissolved fluxes at the sediment water interface of heavy metals and nutrients on the sea bottom in front of the Po River mouths and along the western side of the Northern and Central Adriatic Sea have been determined. The fluxes have been measured by benthic chamber deployments and calculated by pore water modelling. Pore waters composition have been used also to understand the early diagenesis processes generating the benthic fluxes.</p><p>Benthic chamber deployments and sediment core collection for pore water extraction have been carried out in three cruises in spring and autumn 2013 and autumn 2014.</p><p>The study stations have been chosen on the base of previous research results indicating a decreasing heavy metal and organic matter surface content leaving from the Po River mouths (Pérez-Albaladejo et al., 2016). The data obtained have been compared with previous studies carried in the Adriatic Sea (Spagnoli et al. 2010).</p><p>Results of the 2013 and 2014 cruises and of previous investigations indicate a consistent and rapid dissolved benthic flux decreasing going away from the Po River mouths both southward, eastward and northward.</p><p>The decreasing regards the final electron acceptors and the organic matter degradation products and some heavy metals.</p><p>On the whole, different early diagenesis environments have been recognized in the Northern and Central Adriatic Sea: they embrace two end members: from the Po River Prodelta to the Mid Adriatic Depression (MAD) (Spagnoli et al., 2014). In front of the Po River sediments are characterized by high sedimentation rate and by high inputs of fresh marine organic matter, continental organic matter and Fe-oxyhydroxides. These inputs produce high concentrations of organic matter degradation products, strong anoxic environment in the pore waters and high dissolved benthic fluxes. In the MAD the diagenetic environments are characterized by low sedimentation rate and low inputs of reactive organic matter that produce low concentrations of pore-water organic matter degradation products with oxic conditions near the surface and weak benthic fluxes.</p><p>As regard the two major metals involved in the early diagenesis processes (Fe and Mn), they too show dissolved benthic fluxes decreases from the Po River mouths. Also in this case, this trend is attributed to the high Po River dissolved and particulate, anthropogenic and natural, metal inputs that deposit in the surface sediments of the Po Prodelta (Spagnoli and Bergamini, 1997).</p><p>The dissolved benthic fluxes of trace heavy metals (Co, Ni, Zn, Cu, Cd, Pb) indicate that some elements, such as Co and Pb, are clearly adsorbed by the sediment that act, for these two elements as sink. Other elements, such as Cu, don’t show a clear north–south trend s, while other elements, such as Cd, indicate a southward decreasing trend suggesting a behavior affected by the Po River inputs and Fe-Mn-oxyhydroxide cycle.</p>

The determination of the proportion between the biogenic and the fossil-derived fraction in carbon dioxide emissions from industrial stationary sources is a relevant aspect in the frame of the worldwide efforts to reduce greenhouse gas emissions into the atmosphere. In this field the 14C-based method has gained importance over the years and has been included in standard protocols accepted at both the national and international levels. The advantages of the method, based on the large difference in terms of 14C signature between fossil and biogenic carbon, are reviewed as well as some critical aspects related to its application. In particular the results of a study aimed at validating the method by analyzing synthetic gas mixtures produced in a dedicated plant and with a tuneable proportion between fossil and biogenic carbon dioxide are presented.