Four Streptococcus thermophilus strains (Strep. thermophilus BTC, Strep. thermophilus LY03, Strep. thermophilus 480 and Strep. thermophilus Sfi20) have been examined for their exopolysaccharide production capacity. All strains produced a polymer composed of the neutral sugars glucose and galactose, but in different ratios. It was clearly shown that the biosynthesis of exopolysaccharides from Strep. thermophilus LY03 is growth-associated and hence displays primary metabolite kinetics. The monomer ratio of the exopolysaccharide synthesized did not vary throughout the fermentation cycle. The production kinetics and exopolysaccharide yields were strongly dependent on the fermentation conditions. Physical factors such as temperature, pH and oxygen tension as well as chemical factors (medium composition, initial lactose concentration, carbon/nitrogen levels) were of utmost importance.
Document VersionPublisher's PDF, also known as Version of Record (includes final page, issue and volume numbers) Please check the document version of this publication:• A submitted manuscript is the author's version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website.• The final author version and the galley proof are versions of the publication after peer review.• The final published version features the final layout of the paper including the volume, issue and page numbers. Link to publication General rightsCopyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights.• Users may download and print one copy of any publication from the public portal for the purpose of private study or research.• You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal ? Take down policyIf you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. Insights into the temperature dependence of atomic layer deposition (ALD) of Pt using (methylcyclopentadienyl)trimethylplatinum, (MeCp)PtMe 3 , precursor and O 2 are presented, based on a study of reaction products by time-resolved quadrupole mass spectrometry (QMS) measurements. Above 250 • C, Pt ALD proceeds through unhindered O 2 dissociation at the Pt surface, inducing complete and instantaneous combustion of the precursor ligands. Quantification of the QMS data revealed that at 300 • C, approximately 20% of the C-atoms react during the precursor pulse, forming mainly CH 4 (∼18%) balanced by CO 2 (∼2%). The remaining 80% of the C-atoms are combusted during the O 2 pulse. Time-resolved data indicated that the combustion reactions compete with the hydrogenation reactions for the available surface carbon. Combustion reactions were found to be dominant, provided that a sufficient amount of chemisorbed oxygen is available. When the temperature drops below 250 • C, deposition becomes hindered by the presence of a carbonaceous surface layer of partially fragmented and dehydrogenated precursor ligands, formed during the precursor pulse. The carbonaceous layer limits dissociative chemisorption of O 2 and hence combustion reactions (leading to CO 2 ) whereas reduced surface reactivity also limits (de-)hydrogenation reactions (leading to CH 4 ). Below 100 • C, the carbonaceous layer fully prevents O 2 dissociation and ALD of Pt cannot proceed.
Abstract. Based upon a variational principle derived in a preceding paper, expressions for the magneto-elastic buckling values for ferromagnetic or superconducting systems are given. These relations are evaluated for systems of slender beams. Explicit buckling values are calculated for a single ferromagnetic or superconducting beam of arbitrary cross-section, and for systems of two parallel ferromagnetic or superconducting rods. In the analysis needed for the calculation of the intermediate (i.e., rigid-body) and the perturbed magnetic fields, an intensive use of methods inherent in the theory of complex functions is made. In conclusion our results for a set of two superconducting rods are compared with the results of a mathematically less complicated, but also less rigorous, theory.
A variational principle that can serve as the basis for a magneto-elastic stability (or buckling) problem is constructed. For the two cases of soft ferromagnetic media and superconductors, respectively, it is shown how the variational principle directly yields an explicit expression for the buckling value. The formulation starts from a specific choice for a magneto-elastic Lagrangian L (associated with the so-called Maxwell-Minkowski model for magneto-elastic interactions). For the evaluation of the principle the first and second variations of L are calculated both inside and outside the solid magneto-elastic body. Thus, a general buckling criterion, consisting of an expression for the critical field value, together with a set of constraints for the field variables occurring in the right-hand side of this expression, is constructed. Finally, more detailed formulations are given for, successively, soft ferromagnetic bodies and superconductors. Applications to specific structures, yielding explicit numerical values for the magneto-elastic buckling fields, will be given in a forthcoming paper.
The z-coil of an MRI-scanner is modeled as a set of circular loops of strips, or rings, placed on one cylinder. The current in this set of thin conducting rings is driven by an external source current. The source, and all excited fields, are time harmonic. The frequency is low enough to allow for a quasi-static approximation. The rings have a thin rectangular cross-section; the thickness is so small that the current can be assumed uniformly distributed in the thickness direction. Due to induction, eddy currents occur, resulting in a so-called edge-effect. Higher frequencies cause stronger edge-effects. As a consequence, the resistance of the system increases and the self-inductance decreases. From the Maxwell equations, an integral equation for the current distribution in the rings is derived. The Galerkin method is applied, using Legendre polynomials as global basis functions, to solve this integral equation. This method shows a fast convergence, so only a very restricted number of basis functions is needed. The general method is worked out for N (N ≥ 1) rings, and explicit results are presented for N = 1, N = 2 and N = 24.
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