A review is made of current methods for assessing future changes in urban rainfall extremes and their effects on urban drainage systems, due to anthropogenic-induced climate change. The review concludes that in spite of significant advances there are still many limitations in our understanding of how to describe precipitation patterns in a changing climate in order to design and operate urban drainage infrastructure. Climate change may well be the driver that ensures that changes in urban drainage paradigms are identified and suitable solutions implemented. Design and optimization of urban drainage infrastructure considering climate change impacts and co-optimizing these with other objectives will become ever more important to keep our cities habitable into the future.
The mechanism of photocatalytic biomass reforming for H 2 production is far from fully understood. This study uses functionalized graphene dots with Pt-cocatalyst to reform cellulose in an alkaline solution under 1 sun illumination. Reforming of cellulose is initiated with the peeling of its constituent D-glucose units, which subsequently transform into deprotonated isosaccharinic acid (C 6 ). Further degradation of C 6 into molecules C 5 -C 1 proceeds through successive alternation of C-eliminating hydrolysis and photocatalytic oxidation of C 6 derivatives. The C 6 -C 1 species are quantitatively identified using chromatography and mass spectroscopy. The end C-containing product is predominantly HCOO − rather than HCO 3 − (or CO 2 ). The photocatalytic oxidation is accompanied by the photocatalytic reduction of water to produce H 2 . This reforming steadily produced H 2 for 6 days with a negligible rate decay, accomplishing 35% of the theoretical ultimate value for the reforming of cellulose. This study elucidates the detailed mechanism in the photocatalytic reforming of cellulose.
This paper presents a spatial-temporal downscaling approach to describe the linkage between large-scale climate variables for daily scale to annual maximum (AM) precipitations for daily and sub-daily scales at a local site. More specifically, the proposed approach is based on a combination of a spatial downscaling method to link large-scale climate variables as provided by General Circulation Model (GCM) simulations with daily extreme precipitations at a local site and a temporal downscaling procedure to describe the relationships between daily extreme precipitations with sub-daily extreme precipitations using the scaling General Extreme Value (GEV) distribution. The feasibility of the proposed downscaling method has been tested based on climate simulation outputs from two GCMs under the A2 scenario (HadCM3A2 and CGCM2A2) and using available AM precipitation data for durations ranging from 5 minutes to 1 day at 15 raingage stations in Quebec (Canada) for the 1961 -1990 period. Results of this numerical application has indicated that it is feasible to link large-scale climate predictors for daily scale given by GCM simulation outputs with daily and sub-daily AM precipitations at a local site. Furthermore, it was found that AM precipitations at a local site downscaled from the HadCM3A2 displayed a small change in the future, while those values estimated from the CGCM2A2 indicated a large increasing trend for future periods.
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