This study deals with the deagglomeration of nanoparticles in low concentration suspensions in water, protic polar solvent for polymers such as poly(vinyl alcohol) (PVA). The influence of the main parameters of ultrasonication such as time, power and irradiation modes (continuous, pulsed) on the cluster size of aluminium oxide nanoparticles 1 mg/ml in aqueous solutions was investigated. Power-law dependence of size reduction on ultrasonic time was observed. The study indicated an optimum power input, i.e. at higher vibration amplitude the break up of nanoparticle clusters was no better and there was a risk of reagglomeration occurring during a long ultrasonication. Under optimal conditions, continuous and pulsed irradiations showed almost the same efficiency of deagglomeration over a given time. This result provides alternative operating conditions for attaining the smallest size of the alumina aggregates in suspension. The influence of stabilization on the cluster size was also studied. Alumina nanoparticles were stabilized by electrostatic forces against reagglomeration without the need for dispersants, and the enhancement of dispersion stability using electrostatic, steric effects had no significant effect on the aggregate size. On the contrary, the adsorption of high molecular weight polyelectrolytes onto the particle surface could lead to reagglomeration due to material bridges between particle surfaces and even flocculation.

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Hybrid nanocomposites based on crystalline nanoparticles dispersed in polymer matrix have been widely studied in the past few years because of the ability of these materials to combine the properties of organic polymer and inorganic nanoparticles. The aim of this work is to tune the mechanical properties of a piezoelectric polymer by adding nanoparticles to the matrix. In this paper, alumina nanoparticles were dispersed in the copolymer P(VDF-TrFE), which exhibits high piezoelectric coefficient after polarization under high electric field without needing stretching during the polarization process. Transmission electron microscopy and scanning electron microscopy demonstrate the high rate of welldispersed nanoparticles with 10% of alumina nanoparticles added to the matrix. Piezoelectric measurements indicate that P(VDF-TrFE) may be filled by up to 10 wt% of alumina while retaining its high piezoelectric properties and increasing its elastic constant by more than 20%, measured by Brillouin spectroscopy. This work opens a wide range of applications using nanoparticles with nonlinear optical, pyroelectric, magnetic, or ferroelectric properties.