Recent years have seen considerable advances in organic photovoltaics (OPVs), most notably a significant increase in their efficiency, from around 4 % to over 10 %. The stability of these devices, however, continues to remain an issue that needs to be resolved to enable their commercialization. This review discusses the main degradation processes of OPVs and recent methods that help to increase device stability and lifetime. One of the most effective steps that can be taken to increase the lifetime of OPVs is their encapsulation, which protects them from atmospheric degradation. Efficient encapsulation is essential for long-term device performance, but it is equally important for the commercialization of OPVs to strike a balance between achieving the maximum device protection possible and using low-cost processing for their encapsulation. Various encapsulation techniques are discussed herein, with emphasis on their cost effectiveness and their overall suitability for commercial applications.
Polymeric composites have gone through a level of maturity beyond the laboratory stage with the development of the Boeing 787, the structure of which contains more than 50% composites. Nonetheless, a basic understanding of the material used in its primary structure has not been extensively investigated. For instance, micromechanical models are inadequate as they always assume an evenly distributed homogeneous matrix, without following classic lamination theory, which assumes constant stress through the laminate thickness. Our program now in its third year at the Polymeric Composites Laboratory in Seattle, supported by industry as well as government agencies, and in collaboration with several universities on a global scale, is developing such concepts for understanding and improving matrices in layered configurations.This effort focuses on the development of interlayer systems used as enablers to improve certain properties of the composite, such as fracture-toughness and crack-propagation inhibition.
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