Tests are described showing the results obtained for the determination of REE and the trace elements Rb, Y, Zr, Nb, Cs, Ba, Hf, Ta, Pb, Th and U with ICP‐MS methodology for nine basaltic reference materials, and thirteen basalts and amphibolites from the mafic‐ultramafic Niquelândia Complex, central Brazil. Sample decomposition for the reference materials was performed by microwave oven digestion (HF and HNO3, 100 mg of sample), and that for the Niquelândia samples also by Parr bomb treatment (5 days at 200°C, 40 mg of sample). Results for the reference materials were similar to published values, thus showing that the microwave technique can be used with confidence for basaltic rocks. No fluoride precipitates were observed in the microwave‐digested solutions. Total recovery of elements, including Zr and Hf, was obtained for the Niquelândia samples, with the exception of an amphibolite. For this latter sample, the Parr method achieved a total digestion, but not so the microwave decomposition; losses, however, were observed only for Zr and Hf, indicating difficulty in dissolving Zr‐bearing minerals by microwave acid attack.

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Previous studies have proposed that a major suture resulted from the collision between the Amazonian and Sa ˜o Francisco-Congo cratons during the Cambrian, following the closure of a supposed Clymene Ocean. The proposal tentatively located this ocean along the Araguaia and Paraguay belts at the eastern margin of the Amazonian Craton, and its southern extension reached the Pampean belt in Argentina. In the present study we will argue that the existence of Ediacaran-Cambrian oceanic lithosphere in central South America is highly unlikely. West Gondwana was assembled during the convergence between the Amazonian, West African, Sa ˜o Francisco-Congo and Rio de La Plata cratons as well as the Saharan Metacraton, leading to the closure of the Goia ´s-Pharusian Ocean during the Neoproterozoic. Final closure and continental collision resulted in the development of the Transbrasiliano-Kandi mega-shear zone that cuts through several mobile belts, but leaves the cratonic areas totally untouched. Consistent results of radiometric dating along the Transbrasiliano (TB) mega-shear in South America and of metamorphic rocks of the Brası ´lia Belt have indicated that the Neoproterozoic collision finished at ca. 620 Ma. After isostatic uplift, cooling, and denudation, between 590 and 500 Ma, emplacement of undeformed K-rich postorogenic granites represented the main tectonic event. At this time or afterwards, a series of small extensional sedimentary basins formed in graben troughs, most of which are within the TB tectonic corridor. They all were of extensional character, contrasting clearly with the convergent tectonics occurring within the coeval Pampean Orogen in Argentina. The main arguments showing that an Ediacaran to Cambrian oceanic closure in central Brazil is untenable include: (i) the assembly of West Gondwana was completed by ca. 600 Ma, when the convergence between the Amazonian, Sa ˜o Francisco and Rio de La Plata cratons had already ended. After this, there is no geological evidence of an oceanic lithosphere (for example, ophiolites, magmatic arcs, et cetera), ruling out the possible existence of an Ediacaran or Cambrian Clymene Ocean in Central Brazil; (ii) the Gurupi and Araguaia belts in Brazil, as well as the Bassaride and Rokelide belts in West Africa, are regarded as aulacogenic-type systems formed within an intraplate tectonic setting. Their tectonic history precedes the collision between the Amazonian and Sa ˜o Francisco-Congo cratons, as demonstrated by the linear structures of the Transbrasiliano megashear which truncate the N-S structural trends of the Araguaia Belt; (iii) there is a close correlation between the Corumba ´Group of the Paraguay Belt in Brazil and the Arroyo del Soldado Group in Uruguay. These sedimentary sequences belonged to the same Ediacaran continental shelf and this is a powerful indicator for an Ediacaran connection between the Amazonian and Rio de La Plata cratons, which precludes the existence of a wide ocean (for example, the Clymene) between them. On