Plant biomass is considered the main source of renewable carbon raw materials, which is a viable alternative to crude oil and natural gas and provides compounds with a low carbon footprint. The most promising direction for the conversion of biomass is the synthesis of 5-hydroxymethylfurfural, which is regarded as a platform chemical, the basis for the synthesis of valuable compounds, including monomers and polymers. The move of the polymer industry to renewable plant materials will contribute to solving global environmental problems and ensure the sustainability and environmental safety of plastics production. This review analyzes recent advances in the preparation of key C6-furan platform chemicals, such as 5-hydroxymethylfurfural, 2,5-furandicarboxylic acid, 2,5-diformylfuran, 2,5-bis(hydroxymethyl)furan, levulinic acid, and their use for the production of monomers and polymers based on renewable plant biomass. Production processes of widely known furan polyesters and polyamides, such as polyethylene-, polypropylene-, polybutylene furanoates, polyhexamethylene furanamide, are considered, as well as developments towards novel promising materials that are furan copolymers and polymer mixtures. For the first time, studies have been systematized aimed at converting liquid and solid wastes of the synthesis of platform chemicals, known as humins, into a range of value-added products, including organic compounds, porous carbon materials, thermosetting binders, and anticorrosive coatings that can replace similar materials based on fossil raw materials. Economic and environmental prospects and problems of production and consumption of furan polymers are considered. The bibliography includes 275 references.

Biomass processing wastes (humins) are anticipated to become a large-tonnage solid waste in the near future, owing to the accelerated development of renewable technologies based on utilization of carbohydrates. In this work, the utility of humins as a feedstock for the production of activated carbon by various methods (pyrolysis, physical and chemical activation, or combined approaches) was evaluated. The obtained activated carbons were tested as potential electrode materials for supercapacitor applications and demonstrated combined micro- and mesoporous structures with a good capacitance of 370 F g (at a current density of 0.5 A g ) and good cycling stability with a capacitance retention of 92 % after 10 000 charge/discharge cycles (at 10 A g in 6 m aqueous KOH electrolyte). The applicability of the developed activated carbon for practical usage as a supercapacitor electrode material was demonstrated by its successful utilization in symmetric two-electrode cells and by powering electric devices. These findings provide a new approach to deal with the problem of sustainable wastes utilization and to advance challenging energy storage applications.

A new method was developed for the selective gram-scale synthesis of 2,5-diformylfuran (DFF), which is an important chemical with a high application potential, via oxidation of biomass-derived 5-hydroxylmethylfurfural (HMF) catalyzed by 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl (4-AcNH-TEMPO) in a two-phase system consisting of a methylene chloride and aqueous solution containing sodium hydrogen carbonate and potassium iodide. The key feature of this method is the generation of the I2 (co-)oxidant by anodic oxidation of iodide anions during pulse electrolysis. In addition, the electrolyte can be successfully recycled five times while maintaining a 62-65 % yield of DFF. This novel method provides a sustainable pathway for waste-free production of DFF without the use of metal catalysts and expensive oxidants. An advantage of electrooxidation is utilized in the preparation of demanding chemical.

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