The
new generation of glucose biosensors has gained immense research
interest owing to its cost effectiveness, quick response, good stability,
reproducibility, and low detection limit. The enzymatic glucose sensor
suffers from numerous intrinsic disadvantages; therefore, there is
a need to develop a new biosensor which can overcome the disadvantages
of enzymatic glucose biosensors. In that context, metal oxide-based
nanostructures and their compostites exhibit properties that can overcome
the drawbacks of enzymatic glucose sensors. This review discusses
recent developments in some of the metal oxides (CoO, NiO, CuO, and
ZnO) along with their composites as well as their applications toward
nonenzymatic glucose sensors. The metal oxide composites possess excellent
features which signify the potential commercial applications of metal
oxide-based composites for nonenzymatic electrochemical glucose sensing.
Two-dimensional graphene oxide (GO) nanosheets with high electrical conductivity and electrochemical stability are employed as a hybridization matrix to improve the electrode performance of layered double hydroxides (LDHs). A cobaltchromium-LDH hybridized with a GO matrix leads to anchored Co-Cr-LDH-GO (CCG) self-assembly with a high surface area, mesoporous morphology, high electrical conductivity, and high charge transfer kinetics. The CCG nanohybrids display enhanced specific capacity (1502 C g −1 ) with high-rate characteristics compared to pristine Co-Cr-LDH (591 C g −1 ), signifying the crucial role of GO as a hybridization matrix for improving the electrode performance of LDH materials. Aqueous and all-solid-state hybrid supercapacitors are fabricated using the best-optimized CCG nanohybrid and reduced graphene oxide as an anode and a cathode, respectively. The aqueous device delivers a specific capacitance of 181 F g −1 , a specific energy (SE) of 56.66 Wh kg −1 , and a specific power (SP) of 600 W kg −1 at 0.8 A g −1 . Moreover, the solid-state device delivers a specific capacitance of 130.8 F g −1 , a SE of 46.50 Wh kg −1 , and a SP of 1536 W kg −1 at 1.92 A g −1 . The present study clearly demonstrates the usefulness of conducting GO as an efficient hybridization matrix to improve the electrode performance of LDHs.
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