The photovoltaic (PV) sector has undergone both major expansion and evolution over the last decades, and currently, the technologies already marketed or still in the laboratory/research phase are numerous and very different. Likewise, in order to assess the energy and environmental impacts of these devices, life cycle assessment (LCA) studies related to these systems are always increasing. The objective of this paper is to summarize and update the current literature of LCA applied to different types of grid-connected PV, as well as to critically analyze the results related to energy and environmental impacts generated during the life cycle of PV technologies, from 1st generation (traditional silicon based) up to the third generation (innovative non-silicon based). Most of the results regarded energy indices like energy payback time, cumulative energy demand, and primary energy demand, while environmental indices were variable based on different scopes and impact assessment methods. Moreover, the review work allowed to highlight and compare key parameters (PV type and system, geographical location, efficiency), methodological insights (functional unit, system boundaries, etc.), and energy/environmental hotspots of 39 LCA studies relating to different PV systems, in order to underline the importance of these aspects, and to provide information and a basis of comparison for future analyses.

Over the years, different types of smart windows have been tested and developed. In this study, an innovative prototype of a photovoltaic smart window, that integrates luminescent solar concentrators, was analysed. The device independently regulates the movement of the shading system and allows energy surplus, through the electricity generated by modules. Considering the peculiar structure (characterized by the presence of a light shelf) and the thermal characteristics of the device, the analyses focused on optical, thermal, and electrical performances, comparing them with those of a traditional window. The analysis followed an experimental approach that involved lighting and electrical monitoring studies in a real test room, to create validated models for conducting simulations in larger buildings. The results were expressed through the study of illuminance maps, electricity generation obtainable from the integrated photovoltaic technology and in terms of energy savings. Energy generation accounts for around 10 Wh/month, with up to 50% improvement from the perspective of energy use for heating and cooling. The technology proves effective in allowing efficient overall energy performances while generating enough energy to operate the smart window control systems.

The main goal of this paper is to assess the life cycle environmental impacts of a multifunctional smart window luminescent solar concentrator (SW–LSC) prototype through the application of the Life Cycle Assessment methodology. To the authors’ knowledge, this is one of the first studies on the topic. The analysis followed a cradle to gate approach, considering the assembly and maintenance phase as well as the end of life, examined separately through a recycling/landfill scenario. A comparison of the impacts of LSC modules with those of some building-integrated photovoltaic technologies was carried out. Results showed that the global warming potential (100 years) for SW–LSC was 5.91 × 103 kg CO2eq and the manufacturing phase had the greatest impact (about 96%). The recycling/landfill scenario results showed the possibility to reduce impacts by an average of 45%. A dominance analysis of SW–LSC components showed that the aluminum frame was the main hotspot (about 60% contribution), followed by the light-shelf (about 19%). Batteries and motors for the shading system were the biggest contributors in the abiotic depletion potential category (36% and 30%, respectively). An alternative scenario, which involved the use of 75% recycled aluminum for the window frame, highlighted the possibility to reduce environmental impacts from 3% to 46%. Finally, the comparison results showed that the LSC modules’ impacts were on average 870% lower than that of various PV technologies when compared on the basis of m2; on the contrary, LSC modules had the highest impacts in all categories (from 200% to 1900%) when compared with other PV technologies on the basis of 1 kWh of energy generated. The results could be used for the definition of eco-design strategies for the examined device, in order to support the scaling-up process and to put “greener” systems onto the market.