A sensor device based on doped-carbon
quantum dots is proposed
herein for detection of nitrite in meat products by fluorescence quenching.
For the sensing platform, carbon quantum dots doped with boron and
functionalized with nitrogen (B,N-Cdot) were synthesized with an excellent
44.3% quantum yield via a one-step hydrothermal route using citric
acid, boric acid, and branched polyethylenimine as carbon, boron,
and nitrogen sources, respectively. After investigation of their chemical
structure and fluorescent properties, the B,N-Cdot at aqueous suspensions
showed high selectivity for NO2
– in a linear range from 20 to 50 mmol
L–1 under optimum conditions at pH 7.4 and a 340
nm excitation. Furthermore, the prepared B,N-Cdots successfully detected
NO2
– in a real meat sample with recovery of 91.4–104% within the
analyzed range. In this manner, a B,N-Cdot/PVA nanocomposite film
with blue emission under excitation at 360 nm was prepared, and a
first assay detection of NO2
– in meat products was tested using
a smartphone application. The potential application of the newly developed
sensing device containing a highly fluorescent probe should aid in
the development of a rapid and inexpensive strategy for NO2
– detection.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.