Organic-inorganic hybrid materials composed of bismuth and diaminopyridine are studied as novel materials for electron extraction layers in polymer solar cells using regular device structures. The hybrid materials are solution processed on top of two different low band gap polymers (PTB7 or PTB7-Th) as donor materials mixed with fullerene PCBM as the acceptor. The intercalation of the hybrid layer between the photoactive layer and the aluminum cathode leads to solar cells with a power conversion efficiency of 7.8% because of significant improvements in all photovoltaic parameters, that is, short-circuit current density, fill factor, and open-circuit voltage, similar to the reference devices using ZnO as the interfacial layer. However when using thick layers of such hybrid materials for electron extraction, only small losses in photocurrent density are observed in contrast to the reference material ZnO of pronounced losses because of optical spacer effects. Importantly, these hybrid electron extraction layers also strongly improve the device stability in air compared with solar cells processed with ZnO interlayers. Both results underline the high potential of this new class of hybrid materials as electron extraction materials toward robust processing of air stable organic solar cells.

The development of ultrathin dielectrics for low power electronics operations, flexible and printed electronics, and field‐effect‐transistor‐based sensors is still a challenge. Here, monolayers of engineered lipids supported on silicon are reported presenting exceptional mechanical and dielectric properties. The lipid monolayers are stabilized using a simple procedure based on a two‐stage reticulation process in both their aliphatic chains and their head‐group. With a thickness lower than 3 nm, such layers are demonstrated to offer exceptional mechanical and dielectric stability with unprecedented low leakage current and dielectric strength. Surprisingly, the mechanical and dielectric pressures required to rupture/breakdown the monolayers are shown to be similar. These results suggest the presence of a strong correlation between mechanical and dielectric properties, as well as between the mechanisms of rupture and breakdown.

The main purpose of this study is to clarify the factors for the stable operation of a poly(3-hexylthiophene) (P3HT)-based water gated organic field effect transistor (WG-OFET). To this end, the influence of the surface morphologies and electrode metals on the transistor properties were investigated. The experimental results indicated that a flat surface improved the on/off ratio and switching repeatability. Treating the surface with a lipid membrane was found to reduce hysteresis loops in the transfer curves probably due to the reduced number of carrier traps. The Au gate electrode effectively lowered the threshold voltage. Consequently, stable transistor operation with a low threshold voltage of 35 mV was achieved by employing a gold gate electrode and lipid membrane treatment. These results suggest that WG-OFETs with an ultra-thin lipid membrane have great potential for sensor applications, and in particular for sensing water-soluble analytes.