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The hierarchical Zr-MTW zeolites are prepared using NH 4 F and HF as mineralizing agents and structure-directed agent like Gemini-type surfactant and studied by X-ray diffraction (XRD), 29 Si magic angle spinning nuclear magnetic resonance ( 29 Si MAS NMR), Fourier transform infrared (FTIR) spectroscopy with pyridine, 2,6-di-tert-butylpyridine and CD 3 CN as probe molecules. Structural characteristics and acid-base properties of the zeolites depend on concentration of fluorine precursor in the reaction medium (a ratio of Si/F). The hierarchical Zr-MTW zeolites (included doped with copper) have been tested in ethanol conversion into 1,3-butadiene by Lebedev method. The symbatical dependence of 1,3-butadiene productivity with the concentration of Lewis acidic sites determined by FTIR spectroscopy of adsorbed CD 3 CN is observed. 1.3-Butadiene selectivity of 68 % with ethanol conversion of 81 % are achieved in the presence of Cu/Zr-MTW catalyst. [a] M. M. Kurmach, Dr. O. V. Larina, Dr. P. I. Kyriienko, P. S. Yaremov, Dr. O. V. Shvets, Prof. S. O. Soloviev alexshvets@ukr.net [b] Dr.

Compounds 4a–d revealed good catalytic activity and prospects for use as mesomorphic materials.

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