The paper describes a gravimetric method of determining the volatility (evaporation rate) of pesticides. The measuring apparatus may be set at any temperature between ∼15 and 80°C; the dry air flowing through the apparatus is regulated by valves between ‐0.2 1/h and 300 1/h.
Figures available for vapour pressure reveal a mathematical relation between vapour pressure and evaporation rate. This can be used as a simple method of determining the vapour pressure of any substance at 20°C by determining the evaporation rate when the air current is flowing at 50 l/h. The effects of the temperature and the air flow rate on the evaporation rate are also analysed.
Hitherto it has been possible to determine vapour pressures only at a temperature of 20°C when using the method previously described for measuring the evaporation rate. The scope of application of the method has now been extended to temperatures of 30, 40, 50 and 60°C; because of the known temperature dependence of the vapour pressure, the vapour pressures at all the intermediate temperatures can then be calculated from these values.
The vapour pressure of thermally stable substances can be determined easily at ambient pressure using the evaporation rate method. It is possible to measure the evaporation by thermogravimetry in the temperature range from 30°C to 800°C. Vapour pressures as low as 10−10 Pa (10−12 mbar) can be determined with excellent reproducibility.
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