We present a study of Nernst effect in underdoped La(2-x)Sr(x)CuO4 in magnetic fields as high as 28 T. At high fields, a sizable Nernst signal was found to persist in the presence of a field-induced nonmetallic resistivity. By simultaneously measuring resistivity and the Nernst coefficient, we extract the entropy of vortex cores in the vicinity of this field-induced superconductor-insulator transition. Moreover, the temperature dependence of the thermoelectric Hall angle provides strong constraints on the possible origins of the finite Nernst signal above T(c), as recently discovered by Xu et al. [Nature (London) 406, 486 (2000)].
The paraconductivity, originating from critical superconducting order-parameter fluctuations in the vicinity of the critical temperature in a layered superconductor is calculated in the frame of the self-consistent Hartree approximation, for an arbitrarily strong electric field and zero magnetic field. The paraconductivity diverges less steep towards the critical temperature in the Hartree approximation than in the Gaussian one and it shows a distinctly enhanced variation with the electric field. Our results indicate that high electric fields can be effectively used to suppress orderparameter fluctuations in high-temperature superconductors.
Coordination polymerization leads to various metal–organic frameworks (MOFs) with unique physical properties and chemical functionalities. One of the challenges towards their applications as porous materials is to make MOFs optimally conductive to be used as electronic components. Here, it is demonstrated that Co-MOF-74, a honeycomb nano–framework with one–dimensionally arranged cobalt atoms, advances its physical properties by accommodating tetracyanochinodimethan (TCNQ), an acceptor molecule. Strong intermolecular charge transfer reduces the optical band gap down to 1.5 eV of divalent TCNQ and enhances the electrical conduction, which allows the MOF to be utilized for resistive gas- and photo-sensing. The results provide insight into the electronic interactions in doped MOFs and pave the way for their electronic applications.
A detailed study of normal-state magnetotransport properties in (Bi,Pb)~Sr2Ca2Cu30 thin films with a zero-resistance critical temperature T,0=105 K prepared by dc-magnetron sputtering on MgO substrates is reported. Measurements of the electrical resistivity, the magnetoresistance, and the Hall effect are analyzed with regard to contributions of the superconducting order-parameter thermodynamic Auctuations, using theories for two-dimensional, layered superconductors.We have obtained a consistent set of parameters, i.e. , the in-plane coherence length g,b(0) =1.6 nm, the out-of-plane coherence length g, (0) =0.14 nm, and the electron-hole asymmetry parameter P= -0.38. At temperatures below 118 K, we observe a remarkable enhancement (above theoretical predictions) of both the excess Hall effect and magnetoconductivity,whereas no such effect is detected for the zero-field paraconductivity.The above anomalies are attributed to a nonuniform critical temperature distribution inside our samples and can be well explained assuming a Gaussian distribution of T, s with a standard deviation 6T, =2.3 K. The excess Hall effect caused by superconducting fluctuations is negative in the entire accessible temperature range, which indicates, together with the paraconductivity and magnetoconductivity results that the indirect (Maki-Thompson) Auctuation process for (Bi,Pb)2Sr2Ca2Cu30" is vanishingly small at temperatures from T, to 130 K.(2D) to three-dimensional (3D) behavior in the vicinity of T, can be estimated. There has been a considerable discussion whether the results in YBa2Cu307 indicate a 2D behavior, ' with a possible crossover to 3D, or isotropic superconductivity. This question is of substantial interest with regard to the role of coupling along the c axis in the superconducting state.
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