cm -', this being the value of kp corresponding to a Fermi energy of 4 ev. Because the dependence of R on g is given roughly by R~q 4, the uncertainty in the choice of q does lead to considerable uncertainty in R.Comparison of the theoretical and empirical values of q for sodium enables one to say that, for sodium at least, our estimate of R is not in error by more than a factor of 5.By an approximate integration of (1) it is easily
For low acoustic frequencies, a mixture (a porous medium or a suspension) is shown to have an effective density which differs slightly from the density given by Archimedes' principle. This effective density is computed from a physically elementary consideration of viscous, incompressible fluid flow. For higher frequencies, pore or particle size in the mixture becomes comparable with the wavelength of shear waves in the fluid, while still small compared with dilatational wavelength. The theory is extended to such frequencies through the known formula for the fluid's resistance to the oscillations of a rigid sphere. In both cases, the effective compressibility of the mixture is taken to be the volume-average of the component compressibilities. From the effective density and compressibility, the acoustic properties of the mixture are predicted. Predictions are compared with previous theories and with experimental results.
A theory is outlined for the propagation constant in media containing numerous small spherical particles. Using expressions derived by Lamb for the zero and first-order scattering coefficients of a particle free to move in a sound field, an expression for the complex propagation constant is derived whose real part yields a velocity which reduces to the homogeneous case for extremely small particles, and whose imaginary part yields an absorption coefficient identical with that derivable from the viscous-drag theory outlined in a previous paper.
Using both an interferometer and a pulse-reflection method, measurements of sound velocity and absorption at megacycle frequencies have been made on mercury-in-water and bromo-form-in-water emulsions of non-uniform particle size, up to a volume concentration of about 50 percent of emulsified liquid. These materials, though showing considerable deviation from a homogeneous behavior, are found to have a velocity and absorption in good agreement with the theory up to concentration of about 25 percent by volume.
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