Soil–bentonite cut-off walls have been widely used to control landfill pollution but they do not have good chemical compatibility with landfill leachate. Attapulgite can be substituted for bentonite in landfill cut-off walls. However, little is known about the chemical compatibility of attapulgite cut-off walls and leachate. This study experimentally investigated the chemical compatibility of attapulgite cut-off wall specimens with organic and inorganic contaminants and found that a sand–attapulgite cut-off wall has good chemical compatibility with organic contaminants. A CaCl2 solution was used to represent inorganic contaminants, and chemical oxygen demand (COD) was used as an indicator of organic content. The hydraulic conductivity of the cut-off wall initially decreased and then increased to become approximately constant as Ca2+ concentration increased. Changes in COD concentration were divided into a decreasing stage (0–10,000 mg/L) and a constant stage (10,000–40,000 mg/L). The increase or decrease in hydraulic conductivity was by no more than one order of magnitude. The increase in the hydraulic conductivity of the sand–attapulgite cut-off wall is explained in terms of bound water content and pore structure. An increase in Ca2+ concentration decreased the bound water content of the cut-off wall while the CaCl2 solution increased macropore and mesopore volume and decreased small pore volume in the sand–attapulgite cut-off wall. The purpose of this study was to elucidate the chemical compatibility of a sand–attapulgite cut-off wall with organic and inorganic contaminants and to increase the understanding of the interactions between the cut-off wall and the contaminants. The results of this research are informative for improving the application, design, and construction of sand–attapulgite cut-off walls.

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